Composition for surface modification

ABSTRACT

The present invention relates to a composition for surface modification. The composition for surface modification according to the present invention contains a particular carbodiimide-based compound, thus forms a covalent bond without damaging skin, hair, or fabric, and semipermanently provides desired skin or hair surface modification effects or fabric care effects.

BACKGROUND 1. Field of the Invention

The present invention relates to a composition for skin or hair surfacemodification and a composition for fabric care.

2. Discussion of Related Art

Cosmetics and personal care products for skin are products which impartskin conditioning effects, such as softness, moisture, smoothness,elasticity, and the like, which are cosmetically advantageous to skin orhave functions of preventing a wrinkle, whitening, blocking ultravioletrays, antioxidation, imparting fragrance, keratin care, preventing orimproving itching, stimulating hair growth, preventing acne andinhibiting bacteria, suppressing body odor, atopic dermatitis care, porecare, improving roughness, improving skin tone, improving bloodcirculation and stimulating blood flow, stimulating penetration ofactive ingredients and improving a retention time thereof, removing anodor, deodorizing, epilation, dyeing or tattooing with a dye and apowder, fingernail and toenail care, bioconjugation, or the like, andmay further provide functions of cleansing, washing, or the like.Research has been conducted on various methods for enhancing theconditioning effects of the cosmetics and personal care products forskin, and although the products have excellent conditioning effects, theeffects are mostly only temporary.

Therefore, research for not temporarily but semi-permanently keepingconditioning effects on skin is being actively conducted.

Generally, the human's hair cuticle consists of flat overlapping cells(scales). The cuticle cells are attached at the root of the hair andgrow toward the tip of the hair like tiles on a roof. Each cuticle layerhas a thickness of about 0.3 to 0.5 μm, and about 5 to 10 μm of thelayer is visible. The cuticle in human hair is generally formed with 5to 10 layers. Each cuticle cell in a hair consists of a cell membranecomplex and various sublamellar layers such as the epicuticle, A-layer,exocuticle, endocuticle, and inner layer. The outermost layer, theepicuticle, is covered with lipids (fatty acids) covalently bondedthereto, and 18-methyleicosanoic acid (18-MEA) is the most abundantcomponent thereof. This layer constitutes an outer 13-layer of the cellmembrane complex in the cuticle, and serves to provide lubrication,decrease friction, and form a hydrophobic surface.

In a hair, a portion that extends above the scalp is referred to as thehair shaft and is affected by the lifespan and length of a hair. Also,the hair shaft is affected by environmental stresses such as dryness,ultraviolet rays, seawater, calcareous components in a pool, and thelike, and stresses on hair when hair is cut, shampooed, dried using ahair dryer, combed, permed, or colored. In particular, the hair cuticlemaking up the outer part of the hair shaft is damaged by theaccumulation of more than one of such stresses, even when it is notunder the direct influence of such stresses. A damaged hair is in astate in which the hair cuticle is jagged or partially peeled off anddetached to some extent. Such a hair loses its gloss and smoothnessbecause it reflects light diffusely. More progressed damage to a hairleads to complete loss of a hair cuticle layer so that the cortex in thehair is exposed, and thus a hair is split or easily broken.

Various treatments have been attempted to improve the surface of hairhaving damaged 18-MEA. In particular, products providing a hair surfacemodification effect (i.e., a hair reinforcement effect) such as hairmanicure or hair essences by which a hair surface is coated with asilicone are sold or practiced in beauty salons. Particularly, variousproducts which impart a reinforcing effect to hair by coating a hairsurface or allowing amino acids to penetrate into the inside of hair,such as reinforcing shampoo and the like, have been developed in recentyears.

However, when hair is treated with such a hair-modifying component, itonly provides a temporary and short-term effect until the next wash, andthus there is always the inconvenience of re-treating the hair with thehair-modifying component after wash. Therefore, research has beenconducted on various methods for enhancing conditioning effects of thecosmetics and personal care products for hair, and although the productshave excellent conditioning effects, the effects are mostly onlytemporary.

Generally, fabric care refers to functions of imparting a softeningeffect to a fabric, preventing damage caused by light, suppressingformation of a wrinkle in a fabric, allowing the formed wrinkle to beeasily removed, vivifying the original color of a fabric, maintainingthe original feeling of color thereof for a long time, allowing surfacecontamination to be easily removed, imparting fragrance, removing anodor, repelling bacteria or pests, preventing damage caused by washing,preventing the penetration of rain, and the like.

A composition for fabric care may commonly include a composition withfunctions advantageous to a fabric such as washing, regulating, orpointing of a fabric, or the like and a composition with functionsadvantageous to a fabric such as dyeing, bleaching, softening, orsterilization of a fabric, blocking ultraviolet rays, applying afragrance to a fabric, or the like for caring a fabric.

Examples of a product prepared by formulating such a composition includea detergent, a softener, a fabric rinse, a treatment, a partiallytreating agent, and the like.

Examples of a raw material commonly used to constitute such acomposition for fabric care include an oil-soluble raw material such asoils and fats, waxes, hydrocarbon, higher fatty acids, higher alcohols,ester oils, silicone oils, and the like, a polymer compound used as ananionic, cationic, amphoteric, or nonionic surfactant, a moisturizer, athickener, or a film former, a ultraviolet ray absorbent and aultraviolet ray blocker, an antioxidant, a chelating agent, an ionexchanger, a builder, a bleaching agent, an enzyme, a foam controllingagent, a fluorescence brightening agent, a dye migration proofing agent,a coloring material such as a dye or a pigment, a fragrance, apreservative, and the like.

In addition, as a fabric care component for providing a specificfunctionality, a component for imparting a softening effect to a fabric,preventing damage caused by light, suppressing formation of a wrinkle ina fabric, allowing the formed wrinkle to be easily removed, vivifyingthe original color of a fabric, maintaining the original feeling ofcolor thereof for a long time, allowing surface contamination to beeasily removed, imparting fragrance, removing an odor, repellingbacteria or pests, preventing damage caused by washing, preventingpenetration of rain or the like, or the like may be included in thecomposition for fabric care. Specifically, the fabric care component maybe a soap, an alkylbenzene sulfonate, an alkane sulfonate, analpha-olefin sulfonate, an alpha-sulfo fatty acid ester, an alkylsulfate, an alkyl ether sulfate, an alcohol ethoxylate, an alkylphenolethoxylate, a fatty acid alkanolamide, an alkylamine oxide, amethylglucamide, an alkyl polyglucoside, distearyl dimethyl ammoniumchloride, an imidazolium derivative, alkyl dimethylbenzene ammoniumchloride, an esterquat, an amino ester salt, an alkyl betaine, an alkylsulfobetaine, sodium carbonate, calcium carbonate, sodium silicate,sodium triphosphate, nitrotriacetic acid, a polycarboxylate, a zeolite,sodium polycarboxylate, sodium polyacrylate, sodium hydroxyethanediphosphate, sodium perborate, sodium percarbonate, peroxide,hypochlorite, tetraacetylethylenediamine, sodiump-nonanoyloxybenzenesulfonate, sodium percarbonate, a sodium perborate,a protease, a lipase, a starch degrading enzyme, a pectinase, acellulase, carboxymethyl cellulose, carboxy methyl starch, a celluloseether, a polyethylene terephthalate/polyoxyethylene terephthalatecopolymer, a fatty acid amide, a fatty acid alkanolamide, an amineoxide, stilbene, coumarin, bisbendazole, distyrylbiphenyl,polyvinylpyrrolidone, a polyvinylpyridine oxide, a fragrance, acyclodextrin, sodium sulfate, a silicone or a derivative thereof, analkylamine, a fatty alcohol, a fatty acid, polyethylene, magnesiumchloride, calcium chloride, sodium chloride, and sodium acetate, or thelike.

However, when a fabric is treated with such a fabric care component, itonly provides a temporary and short-term effect until the next wash, andthus there is always the inconvenience of re-treating the fabric withthe hair-modifying component after wash.

In Japanese Laid-Open Patent Application No. 2004-182731, a cosmetictreatment method for maintaining long-lasting cosmetic characteristicsin hair, which has a composition similar to that of skin or a woolfabric, is disclosed. In this technology, a process of primarilyactivating hair through a physical method using heat, electromagneticwaves, electric fields, sound waves, plasma, or the like, which causes achange in a hair surface, or a chemical method excluding reductionshould be performed before hair is subjected to cosmetic treatment.However, in the process of activating hair, high energy such as heat,electromagnetic waves, electric fields, sound waves, plasma, or the likeneeds to be applied to hair, an oxidizing agent such as hydrogenperoxide, bromate, and the like used as a material for chemicaldeactivation other than reduction causes severe damage to hair, andpolyamines or polysaccharide polymers other than the oxidizing agent maybe able to activate hair but are not covalently bonded with hair whileactivating hair and thus are easily removed by washing.

In Korean Unexamined Patent Publication No. 2008-0064467, a non-aqueouspersonal care product for skin or hair is disclosed. In the personalcare product for skin or hair which consists of a non-aqueous part andan aqueous part, the non-aqueous part includes a hair surface-modifyingcomponent having one or more selected from the group consisting offunctional groups capable of covalently bonding with a protein residuein a hair or skin surface, such as carbonates, aldehydes,propionaldehyde, butylaldehyde, nitrophenyl carbonate, aziridines,isocyanate, thiocyanate, epoxides, tresylates, succinimide,hydroxysuccinimidyl esters, imidazole, oxycarbonylamidazole, imines,thiols, vinylsulfone, ethyleneimine, thioethers, acrylonitrile, acrylicor methacrylic acid ester, disulfides, ketones, and functional groupsrepresented as RX (here, R is any one selected from the group consistingof alkyls, aryls, aralkyls, rings, and unsaturated rings, and X is I,Br, or Cl), and the non-aqueous part and the aqueous part are mixedimmediately before using the product. However, various functional groupsas described above are harmful to humans, or target, among amino acidsof proteins constituting hair or skin, lysine contained in a smallamount in hair and skin keratin (1.9 to 3.1% in hair and 3.1 to 6.9% inskin keratin) or cysteine contained in a small amount in hair and skinkeratin (16.6 to 18% in hair and 2.3 to 3.8% in skin keratin) toparticipate in a reaction. Therefore, reaction efficiency is degraded,and each material needs to be synthesized separately.

In Korean Unexamined Patent Publication No. 2002-0068427, a method ofusing chitosan as an antibacterial component and adding amicroencapsulated fragrance to impart long-lasting fragrance and anantibacterial effect to a fabric in addition to softening a fabric iscontemplated. When a fragrance is microencapsulated as described above,the capsule protects the fragrance of a core material from an externalenvironment and improves storage stability of the same, and thus thefragrance of a fabric persists longer. However, since the fragrancecapsules also do not remain on a fabric surface and most of them arewashed away during a washing process, there are a limitation inproviding such effects using only the remaining capsule components in afabric and an economical problem in which most of the capsules thus usedfail to exert their functions and are rinsed by rinsing water.

SUMMARY OF THE INVENTION

It is an aspect of the present invention to provide a composition forskin surface modification capable of semi-permanently and continuouslyimparting a surface modification effect without causing damage to skin.

It is another aspect of the present invention to provide a compositionfor hair surface modification capable of semi-permanently andcontinuously imparting a surface modification effect without causingdamage to hair.

It is still another aspect of the present invention to provide acomposition for fabric care capable of semi-permanently and continuouslyimparting a fabric care effect without causing damage to a fabric.

In order to accomplish the above objectives, according to an embodimentof the present invention, there is provided a composition for skinmodification, which includes a carbodiimide-based compound representedby Chemical Formula 1 below; and a skin-modifying component:

In Chemical Formula 1, A represents a monomer which is one or moreselected from structures listed below and has an isocyanate group (*) atboth termini of a repeat unit thereof, wherein the two As arehomopolymers with the same structure or heteropolymers with mutuallydifferent structures, R represents hydrogen; C1 to C500 linear,branched, or cyclic hydrocarbon; or aromatic hydrocarbon, wherein aportion of the hydrocarbon molecule includes a double bond, issubstituted with one or more elements selected from the group consistingof O, N, S, P, and Si, is substituted in an anionic, cationic, oramphoteric form, or is bonded with a metal ion in a salt form, and m isan integer ranging from 1 to 100.

According to another embodiment of the present invention, there isprovided a skin care product including the composition for skin surfacemodification.

According to still another embodiment of the present invention, there isprovided a composition for hair modification, which includes acarbodiimide-based compound represented by Chemical Formula 1 below; anda hair-modifying component:

In Chemical Formula 1, A represents a monomer which is one or moreselected from structures listed below and has an isocyanate group (*) atboth termini of a repeat unit thereof, wherein the two As arehomopolymers with the same structure or heteropolymers with mutuallydifferent structures, R represents hydrogen; C1 to C500 linear,branched, or cyclic hydrocarbon; or aromatic hydrocarbon, wherein aportion of the hydrocarbon molecule includes a double bond, issubstituted with one or more elements selected from the group consistingof O, N, S, P, and Si, is substituted in an anionic, cationic, oramphoteric form, or is bonded with a metal ion in a salt form, and m isan integer ranging from 1 to 100.

According to yet another embodiment of the present invention, there isprovided a hair care product including the composition for hair surfacemodification.

According to yet another embodiment of the present invention, there isprovided a composition for fabric care, which includes acarbodiimide-based compound represented by Chemical Formula 1 below; anda fabric care component:

In Chemical Formula 1, A represents a monomer which is one or moreselected from structures listed below and has an isocyanate group (*) atboth termini of a repeat unit thereof, wherein the two As arehomopolymers with the same structure or heteropolymers with mutuallydifferent structures, R represents hydrogen; C1 to C500 linear,branched, or cyclic hydrocarbon; or aromatic hydrocarbon, wherein aportion of the hydrocarbon molecule includes a double bond, issubstituted with one or more elements selected from the group consistingof O, N, S, P, and Si, is substituted in an anionic, cationic, oramphoteric form, or is bonded with a metal ion in a salt form, and m isan integer ranging from 1 to 100.

According to yet another embodiment of the present invention, there isprovided a fabric care product including the composition for fabriccare.

DETAILED DESCRIPTION OF EXEMPLARY EMBODIMENTS

Hereinafter, the present invention will be described with reference toexamples and comparative examples in detail. However, the presentinvention is not limited to these examples.

The present invention relates to a composition for surface modificationwhich includes a carbodiimide-based compound and a surface-modifyingcomponent.

The surface-modifying component is a skin surface-modifying component, ahair surface-modifying component, or a fabric surface-modifyingcomponent (fabric care component).

The term “skin” used herein refers to a tissue covering the body, andgenerally includes facial skin, the scalp, body skin, fingernails andtoenails which are accessory organs of the skin, and the like.

The composition for skin surface modification according to the presentinvention may maximize a skin surface modification effect by formingcovalent bonds with proteins in the skin without causing damage to skin,for example, as mediated by a reactive skin surface-modifying componentbonded with a carbodiimide group which is formed by reacting aconventionally known skin surface-modifying component with acarbodiimide-based compound.

The composition for hair surface modification according to the presentinvention may maximize a hair surface modification effect by formingcovalent bonds with proteins in the hair, for example, as mediated by areactive hair surface-modifying component bonded with a carbodiimidegroup which is formed by reacting a conventionally known hairsurface-modifying component with a carbodiimide-based compound.

The composition for fabric surface modification (composition for fabriccare) according to the present invention may maximize a fabric careeffect by forming covalent bonds with proteins in the fabric, forexample, as mediated by a reactive fabric care component bonded with acarbodiimide group which is formed by reacting a conventionally knownfabric care component with a carbodiimide-based compound.

The carbodiimide-based compound generally refers to a compound having astructure represented by Chemical Formula 1 below in a molecule thereof:

In Chemical Formula 1, m is an integer ranging from I to 100, Arepresents a monomer which is one or more selected from structureslisted below and has an isocyanate group (*) at both termini of a repeatunit thereof, wherein the two As are homopolymers with the samestructure or heteropolymers with mutually different structures, and Rrepresents hydrogen; C1 to C500 linear, branched, or cyclic hydrocarbon;or aromatic hydrocarbon, wherein a portion of the hydrocarbon moleculeincludes a double bond, is substituted with one or more elementsselected from the group consisting of O, N, S, P, and Si, is substitutedin an anionic, cationic, or amphoteric form, or is bonded with a metalion in a salt form, but the present invention is not limited thereto.The cyclic hydrocarbon may include a structure including one or moreelements selected from the group consisting of O, N, and Si and/or adouble bond in a ring.

In the present invention, a preferable example of the carbodiimide-basedpolymer may be a carbodiimide-based compound represented by ChemicalFormula 2 below in which the terminal of the polymer is blocked withpolyethylene glycol or polypropylene glycol.

In Chemical Formula 2, A represents a monomer which is one or moreselected from structures listed below and has an isocyanate group (*) atboth termini of a repeat unit thereof, wherein the two As arehomopolymers with the same structure or heteropolymers with mutuallydifferent structures, m is an integer ranging from Ito 100, and n is aninteger ranging from Ito 1,000.

In the present invention, a more preferable example of thecarbodiimide-based polymer may be a carbodiimide-based compoundrepresented by Chemical Formula 3 below.

In Chemical Formula 3, n is an integer ranging from I to less than 120(preferably an integer ranging from 1 to less than 100, and morepreferably an integer ranging from 1 to less than 70), and m is aninteger ranging from 1 to less than 100 (preferably an integer rangingfrom 1 to less than 30, and more preferably an integer ranging from 1 toless than 10).

In the present invention, the most preferable example of thecarbodiimide-based polymer may be1,1′-methylene-bis-(3-isocyanatocyclohexane)-, homopolymer, andpolyethylene glycol mono-Me-ether-blocked, which is a carbodiimide-basedcompound represented by Chemical Formula 3 in which m is an integerranging from 1 to 7 and n is an integer ranging from 5 to 50.

In Chemical Formula 1, when there are more than 100 carbodiimide groupsin one molecule, the viscosity of a raw material becomes too high, andthe molecule has an excessively large molecular weight and too manyreaction sites. In addition, since the size of the molecule havingcarbodiimide groups becomes excessively large, a portion in the moleculeexhibiting a substantial functionality is blocked, and thus efficiencyis degraded.

In the present invention, specific examples of the carbodiimide-basedcompound include 1,1′-methylene-bis-(4-isocyanatocyclohexane)-,homopolymer, polyethylene glycol mono-Me-ether-blocked; 1F-methylene-bis-(3-isocyanatocyclohexane)-, homopolymer, polyethyleneglycol mono-Me-ether-blocked;1,1′-methylene-bis-(4-isocyanatocycloheptane)-, homopolymer,polyethylene glycol mono-Me-ether-blocked;1,1′-methylene-bis-(3-isocyanatocycloheptane)-, homopolymer,polyethylene glycol mono-Me-ether-blocked;1,1′-methylene-bis-(3-isocyanatocyclopentane)-, homopolymer,polyethylene glycol mono-Me-ether-blocked;1,3-bis(isocyanatomethyl)cyclohexane-, homopolymer, polyethylene glycolmono-Me-ether-blocked; benzene-1,3-diisocyanate-, homopolymer,polyethylene glycol mono-Me-ether-blocked; hexamethylene diisocyanate-,homopolymer, polyethylene glycol mono-Me-ether-blocked; PEG 600diisocyanate-, homopolymer, polyethylene glycol mono-Me-ether-blocked;diphenylmethane-2,2′-diisocyanate-, homopolymer, polyethylene glycolmono-Me-ether-blocked; isophorone diisocyanate-, homopolymer,polyethylene glycol mono-Me-ether-blocked; and the like, but the presentinvention is not limited thereto.

Structure of A Compound in Chemical Formula 21,3-Bis(isocyanatomethyl)cyclohexane-, homopolymer, polyethylene glycolmono-Me- ether-blocked 

Benzene-1,3-diisocyanate-, homopolymer, polyethylene glycolmono-Me-ether-blocked 

Hexamethylene diisocyanate-, homopolymer, polyethylene glycolmono-Me-ether-blocked 

PEG 600 diisocyanate-, homopolymer, polyethylene glycolmono-Me-ether-blocked 

Diphenylmethane-2,2′-diisocyanate-, homopolymer, polyethylene glycolmono-Me- ether-blocked 

Isophorone diisocyanate-, homopolymer, polyethylene glycolmono-Me-ether-blocked 

The carbodiimide-based compound may be used at a content of 0.0001 to 10parts by weight, 0.001 to 7 parts by weight, or 0.01 to 5 parts byweight with respect to 100 parts by weight of the entire cosmeticcomposition. When the content of the carbodiimide-based compound is lessthan 0.0001 parts by weight, it is difficult for a surface modificationeffect to persist, and when the content thereof is greater than 10 partsby weight, an excess number of carbodiimide-based compounds as comparedto the number of reaction sites in skin reacts with an effectiveingredient and not with the skin and thus may act as a component whichdoes not help improve persistence and is lost.

The term “skin surface modification” used herein refers to changing theproperties of a skin surface by applying a composition to the skin. Thecomposition may serve to remove dead skin cells or preventkeratinization by coating skin or bonding an active ingredient with skinso as to improve roughness of a skin surface; improve blood circulationor stimulate blood flow so as to make the skin look bright (skin toneimprovement); impart beneficial properties to skin through conditioningeffects including supplementing nutrition to skin and scalp andimparting elasticity, softness, smoothness, and the like to skin so asto beautify the skin, increase attractiveness, and change an appearance;impart a fragrance or suppress body odor; prevent or improve skintrouble such as itching, atopic dermatitis, and the like; stimulate hairgrowth; prevent acne; tighten pores; stimulate the penetration of anactive ingredient; improve a retention time of an active ingredient;moisturize the skin; or block ultraviolet rays to keep the skin healthy,and may be applied to the skin, scattered on the skin, or used by othersimilar methods. For example, skin surface modification effects ofimproving a skin wrinkle, enhancing moisture in skin, supplyingnutrition to skin, maintaining skin water homeostatic, removing andreducing dead skin cells, preventing skin trouble, preventing skinaging, skin antioxidation, preventing scalp dandruff, stimulating skinblood circulation, maintaining and improving skin gloss and elasticity,preventing rough skin and chapped skin, and the like may be exhibited.

The term “hair surface modification” used herein refers to changing theproperties of a hair surface by applying a composition to the hair. Acomposition changes the properties of a hair surface by coating hair orbonding an active ingredient with hair, and thus may serve to impartbeneficial properties to hair through conditioning effects such asmaking hair appear thick, improving split and damaged hair, preventinghair from being split or broken, reinforcing tensile strength, enhancingthickness, hair enrichment, supplying nutrition, enhancing elasticityand gloss, moisturizing, preventing damage, repairing damage, dyeing,bleaching, styling, decreasing friction, penning, removing chlorine,removing saltiness, preventing static electricity, decreasing porosity,volumizing, reducing fuzziness, strengthening curls, forming a film anda thin film, softening, eliminating frizz, enhancing smoothness, and thelike so as to beautify the hair, increase attractiveness, and change anappearance; moisturizing the hair; or block ultraviolet rays to keep thehair healthy, and may be applied to the hair, scattered on the hair, orused by other similar methods. For example, hair surface modificationeffects of antioxidation, conditioning, moisturizing, blockingultraviolet rays, applying a fragrance, a dye, or a powder,bioconjugation, inhibiting bacteria, preventing and improving dandruff,stimulating hair growth, stimulating hair regrowth, and the like may beexhibited, but the present invention is not limited thereto.

The term “fabric care effect” used herein refers to a function ofimparting a softening effect to a fabric, preventing damage caused bylight, suppressing formation of a wrinkle in a fabric, allowing theformed wrinkle to be easily removed, vivifying the original color of afabric, maintaining the original feeling of color thereof for a longtime, dyeing a fabric, allowing surface contamination to be easilyremoved, imparting fragrance, removing an odor, repelling bacteria orpests, preventing damage caused by washing, preventing penetration ofrain and the like, reinforcing penetration into the inside of a fabric,allowing a fabric to be easily ironed, allowing a fabric to be quicklydried, imparting gloss to a fabric, imparting elasticity to a fabric,preventing a contaminant from being easily adhered to a fabric,preventing static electricity, strengthening a fabric, thickening afabric, forming a coating on a fabric surface, providing moisture,reinforcing heat insulation and cold insulation, preventing oxidation,blocking ultraviolet rays, stimulating penetration of an activeingredient into a fabric or improving a retention time thereof, reducingthe occurrence of fluff, preventing a fabric from being entangled, orenhancing skin friendliness of a fabric.

The term “skin surface-modifying component” used herein may be acomponent for antioxidation; conditioning (imparting gloss to the skin);moisturizing; whitening; blocking ultraviolet rays; imparting fragrance;preventing or improving a wrinkle; keratin care; preventing or improvingdandruff/itching; stimulating hair growth; preventing acne or inhibitingbacteria; suppressing body odor; atopic dermatitis care; pore care;epilation; fingernail and toenail care; or bioconjugation, or acomponent in the form of a dye or a powder, but the present invention isnot limited thereto.

The term “hair surface-modifying component” used herein may be acomponent for antioxidation, conditioning (enhancing tensile strength,thickness, elasticity, or gloss, moisturizing, preventing damage,repairing damage, preventing the hair from being split, reducing a breakin the hair, improving splitting of the hair, nourishing, dyeing,bleaching, styling, decreasing friction, perming, removing chlorine,removing saltiness, preventing static electricity, decreasing porosity,volumizing, hair enrichment, reducing fuzziness, strengthening curls,forming a film and a thin film, softening, eliminating frizz, orenhancing smoothness), moisturizing, blocking ultraviolet rays, applyinga fragrance or a dye, bioconjugation, inhibiting bacteria, stimulatinghair growth, stimulating hair regrowth, or the like, but the presentinvention is not limited thereto.

The antioxidation component among the skin-modifying components or thehair-modifying components may be an antioxidation component with anability to significantly reduce or prevent the destruction and depletionof the function and structure of skin damaged by oxidation, such asextracts derived from natural materials such as animals, plants,minerals, and the like, fermented extracts, amino acids, peptides,proteins, and the like, but the present invention is not limitedthereto. For example, the antioxidation component may be one or moreselected from the group consisting of acetamido caproic acid, acetylbenzoyloxy prasterone, acetylcysteine, 2-acetylhydroquinone,adamantanylcarboxamido hydroxylbenzamide, aminoethanesulfinic acid,aminopropyl ascorbyl phosphate, angoroside C, anserine, apigenin,arbutin, alpha-arbutin, ascorbic acid, asiaticoside, benzoguanamine,butylhydroxyanisol (BHA), butylated hydroxytoluene (BHT),bis-hydroxyethyl tocopherylsuccinoylamido hydroxypropane,bis-(tetramethyl hydroxypiperidinyl)sebacate), butylated xylenol,t-butylbenzamido hydroxylbenzamide, 4-butylresorcinol, caffeic acid,calcium ascorbate, carnosic acid, carotenoids, chitosan ascorbate,chlorogenic acid, cobalt DNA, copper adenosine triphosphate (ATP),copper pyridoxal 5-phosphate, curcumin, cysteine, cysteine hydrochloride(HCl), decapeptide-6, decapeptide-7, decursinol, decylmercaptomethylimidazole, diamylhydroquinone, di-t-butylhydroquinone,dicetyl thiodipropionate, dicyclopentadiene/t-butylcresol copolymer,digalloyl trioleate, diisooctyl sebacate, dilauryl thiodipropionate,dimethoxybenzamido phenylhydroxylacetamide, dimethoxy di-p-cresol,dimethylmethoxy chromanol, dimyristyl thiodipropionate, dioleyltocopheryl methylsilanol, diosmine, diretinyl ether, disodium ascorbylsulfate, distearyl thiodipropionate, ditridecyl thiodipropionate,dodecyl gallate, dunaliella bardawil powder, ellagic acid,epigallocatechin gallate, ergothioneine, Eriobotrya japonica leafprotoplasts, erythorbic acid, ethylbisiminomethlguaiacol manganesechloride, ethyl ferulate, ethylhexyl ferulate, ferulic acid, feruloylsoy glycerides, furfuryl palmitate, genistein glucoside, Ginkgo leafterpenoids, glucosylrutin, glyceryl chromonyl ether, glyceryldiferulate, hesperetin, hexyloxy trimethylphenol, honokiol, hydrolyzedproanthocyanidin, hydroquinone, p-hydroxyanisole, hydroxydecylubiquinone, hydroxylamine hydrochloride (HCl), hydroxylamine sulfate,hydroxyphenyl dihydroxybenzamide, inositol hexaniacinate hexaascorbate,isooctyl caprylate/caprate, isooctyl thioglycolate, isoquercitrin,kaempferol, kojic acid, kojyl glucoside, kojyl methylenedioxycinnamate,kou-cha ekisu, lycopene, madecassoside, magnesium ascorbate, magnolol,manganese adenosine triphosphate (ATP), matrine, melatonin, methoxyPEG-7 ascorbic acid, methoxytrimethylphenyl dihydroxyphenyl propanol,methyl di-t-butyl hydroxyhydrocinnamate, methylene di-t-butylcresol,methyl methacrylate/trimethoxysilylpropyl methacrylate crosspolymer,methyl myristic acid, niacinamide hydroxybenzoate, nictoflorin,nordihydroguaiaretic acid, octanicotinoyl epigallocatechin gallate,octapeptide-4, oligopeptide-28, paeonol, palmatine, PEG/PPG-2/5tocopheryl ether, perillyl alcohol, phenethyl caffeate, phenylethylresorcinol, phenylthioglycolic acid, phloretin, phloroglucinol,piceatannol, piperlonguminine, porphyridium polysaccharide, potassiumascorbyl tocopheryl phosphate, potassium sulfite, PPG-2 tocophereth-5,propyl gallate, protocatechuic aldehyde, puerarin, pyridoxinehydroxybenzoate, pyridyloxide t-butylnitrone, quercetin,resacetophenone, resorcinol, resveratrol, retinyl formyl aspartamate,rosmarinic acid, rutin, rutinyl succinate, ryoku-cha ekisu, salnacedin,sodium ascorbate, sodium sulfite, sodium tocopheryl phosphate, sodiumerythorbate, sodium phosphono-pyridoxylidenerhodanine, sodiumthioglycolate, sodium zinc histidine dithiooctanamide, sorbitylfurfural, stearyl gallate, succinoyl ascorbate pentapeptide-6,tangeritin, tert-butylhydroquinone (TBHQ), tetrabutylethylidinebisphenol, tetrahydrodemethoxydifendoylmethane,tetrahydrocurcumin diacetate, tetrahydrodiferuloylmethane,tetramethylbutyl dihydroxybenzamide, tetramethylchromanol glucoside,thioctic acid, thiodiglycol, thiolactic acid, thiosalicylic acid,thioaurine, thymol trimethoxycinnamate, tococysteamide, tocophereth-5,tocopherols, tocophersolan, tocopheryl acetate, tocoquinone, toluene,o-tolyl biguanide, totarol, tripropylene glycol, tris-BHT mesitylene,tris(nonylphenyl)phosphite, trisodium ascorbyl isopalmitate phosphate,tyrosyl histidine hydrochloride (HCl), ubiquinol, ubiquinone, Ulvalactuca powder, uuron-cha ekisu, xylyl dibutylbenzofuranone, zincadenosine diphosphate (ATP), zinc dibutyldithiocarbamate, zinc fructosediphosphate, zinc pyridoxal 5-phosphate, and a derivative thereof, butthe present invention is not limited thereto.

The conditioning component among the skin-modifying components or thehair-modifying components may be a component for providing aconditioning effect capable of filling a damaged portion of skin orhair, such as extracts derived from natural materials such as animals,plants, minerals, and the like, amino acids, peptides, proteins, and thelike, but the present invention is not limited thereto. For example, thecomponent having a conditioning effect may be one or more selected fromthe group consisting of natural extracts, amino acids, peptides,proteins, polymers, silicones, fatty alcohols, fatty acids, waxes,esters, fatty amidoamines, hydrocarbons, alky glyceryl esters,polyhydric alcohols, sugars, surfactants, powders and dyes,polyethylene, polypropylene, ceramides, vitamins, alkylamines, alkylamidoamines, and a derivative thereof, but the present invention is notlimited thereto.

The natural material-derived extract may be an algae extract, aHelianthus annuus seed extract, a Sophora flavescens extract, a Panaxginseng root extract, a Coptis chinensis root extract, a Calendulaofficinalis extract, Betula platyphylla sap, a Betula alba extract, aZanthoxylum bungeanum maxim extract, a Luffa cylindrica extract, aMonarda didyma extract, a Chamaecyparis obtusa extract, a Rhodiola roseaextract, a Sophora flavescens extract, an Atractylodes rhizome extract,a Centella asiatica extract, a Coptis chinensis extract, red ginsengroot water, a Fritillaria ussuriensis extract, a Convallaria keiskeiextract, a cassis extract, a pomegranate extract, a lemon extract, apine bud extract, a green tea extract, a broccoli extract, a honeycombextract, a honey extract, propolis, royal jelly, a cranberry extract, aberry extract, a lavender extract, a lentil extract, a ginger extract,or the like. The protein and the peptide may be a protein and a peptidewhich are obtained from Chun-zam silk, silk, polylysine, algae, wool andhair, or wheat, but the present invention is not limited thereto.

The amino acid may be glycine, alanine, valine, leucine, isoleucine,threonine, serine, cysteine, cystine, methionine, aspartic acid,asparagine, glutamic acid, diiodotyrosine, lysine, arginine, histidine,phenylalanine, tyrosine, tryptophan, proline, oxyproline, or the like,but the present invention is not limited thereto.

In addition, the polymer may be a linear/branched chain-type ornetwork-type polymer compound having a molecular weight of about 1,000to 1,000,000, may include a double bond or various ring-structuralsubstituents between carbon atoms as necessary, and preferably includesat least one residue with reactivity in the molecule to attach abioreactive group such as —COONa, —COOK, —COOH, —NH₂, —NHR, —NR₂, —Cl,—Br, —I, or —F for easily attaching a bioreactive functional group toany one terminus of the molecule. More preferably, the polymer is acompound which is a linear/branched chain-type polymer having about10,000 to 500,000 carbon atoms and includes at least one residue withreactivity in the molecule to attach a bioreactive group such as —COONa,—COOK, —COOH, —NH₂, —NHR, —NR₂, —Cl, —Br, —I, or —F for easily attachinga bioreactive functional group to any one terminus of the molecule. Forexample, the polymer may be an amphoteric polymer such as a polyaminepolymer, a polycarboxylic acid polymer, a methacryloyl ethylbetaine/methacryl ate copolymer, or anoctylacrylamide/acrylate/butylaminoethyl methacrylate copolymer, anonionic polymer such as polyvinylpyrrolidone (PVP), a PVP/vinyl acetate(VA) copolymer, or a PVP/dimethylaminoethyl methacrylate copolymer, oran anionic polymer such as an acrylate/methacrylate copolymer or aVA/crotonate/vinyl neodecanoate copolymer, but the present invention isnot limited thereto.

The silicone may be, for example, a compound such as dimethicone,trimethicone, phenyl amodimethicone, amodimethicone, amodi phenyltrimethicone, amodi-penta phenyl trimethicone, dimethylpolysiloxane,methylphenylpolysiloxane, decamethylcyclopentasiloxane, methyltrimethicone, phenyl trimethicone, methicone, cyclomethicone, alkylmethyl siloxane, dimethicone copolyol, or trimethylsilylamodimethicone,but the present invention is not limited thereto.

The fatty alcohol is a C10 to C50 linear/branched fatty alcoholcompound, and preferable examples thereof include lauryl alcohol, cetylalcohol, stearyl alcohol, isostearyl alcohol, behenyl alcohol, and thelike, but the present invention is not limited thereto.

The fatty acid is a C10 to C50 linear/branched fatty acid compound, andpreferable examples thereof include 18-methyl eicosanoic acid, lauricacid, stearic acid, isostearic acid, and the like, but the presentinvention is not limited thereto.

The wax may be, for example, candelilla wax, carnauba wax, ricebran wax,beeswax, lanoline, ozokerite, ceresin wax, paraffin wax,microcrystalline wax, polyethylene wax, or the like, but the presentinvention is not limited thereto.

The ester may be, for example, isopropyl myristate, butyl myristate,isopropyl palmitate, ethyl stearate isopropyl linoleate, decylmyristate, cetyl myristate, cetyl palmitate, hydrogenated polyisobutene,or the like, but the present invention is not limited thereto.

The fatty amidoamine may be, for example, stearyl amidopropyl amine,isostearyl propyl amido amine, stearyl amido amine, isostearyl propylamido amine, methyleicosanoic amidopropyl amine, methyleicosanoicamidoamine, behenyl amidopropyl amine, behenyl amidoamine, or the like,but the present invention is not limited thereto.

The sugar may be diose- to hexose-monosaccharides such asglycolaldehyde, glyceraldehyde, dihydroacetone, erythrose, erythrulose,ribose, arabinose, xylose, ribulose, xylulose, glucose, fructose,galactose, and mannose; disaccharides such as sucrose, maltose, lactose,trehalose, melibiose, and cellobiose; polysaccharides such as raffinose,melezitose, maltoriose, starchiose, oligosaccharides,galactooligosaccharides, isomaltooligosaccharide,fructooligosaccharides, xylan, araban, starch, dextrins, glycogen,cellulose, fructans, galactan, and mannan; or complex polysaccharidessuch as agar, algin, carrageenans, chitin, hemicelluloses, and pectin,but the present invention is not limited thereto.

The ceramide is a material with a structure in which a fatty acid isbonded to the amino group of a sphingosine, and the class of ceramidesincludes natural/synthetic ceramides. For example, the ceramide may besphingosine, sphinganine, sphingenine, 2-amino-4-eicosane-1,3 diol,ceramides, spingomyelin, cerebrosides, gangliosides, sphingolipids, orderivatives thereof, but the present invention is not limited thereto.

The moisturizing component among the skin-modifying components or thehair-modifying components may be a moisturizing component capable offilling a damaged portion of skin or hair, such as extracts derived fromnatural materials such as animals, plants, minerals, and the like, aminoacids, peptides, proteins, sugars, vitamins, and the like, but thepresent invention is not limited thereto. For example, the moisturizingcomponent may be one or more selected from the group consisting ofPPG-arginine, glycerin, propylene glycol, butylene glycol, dipropyleneglycol, caprylyl glycol, diglycerin, methyl gluceth, ethoxydiglycol,glycereth, propanediol, diethoxydiglycol pyrrolidone carboxylic acid,sodium lactate, sodium PCA, mineral oil, vaseline, lanolin, jojoba oil,olive oil, glycosphingolipids, phospholipids, lipid composites, isononylisononanoate, betaines, carboxymethyl chitin, ceramides,glucosylceramide, glycosaminoglycans, alpha-glucans, hyaluronic acid,hydrolyzed hyaluronic acid, betaines, chitosan, chitosan succinamide,vitamin E (tocopherols), urea, hydroxyethyl urea, glucosides, gamma PGA,xylitylglucoside, xylitol, pentaerythrityl tetraisostearate, sodiumchondroitin sulfate, chondroitin-4-sulfate, atelocollagen, beta-glucan,PEG, pyridoxine tris-hexyl decanoate, potassium PCA, sodiumpolygamma-glutamate, polyglutamic acid, glyceryl polyacrylate,galactoarabinan, polyglycerin-3 crosspolymer, sodium hyaluronate,bis-PEG-18 methyl ether dimethyl silane, bis-ethoxydiglycol succinate,lecithin, ascorbyl tetraisopalmitate, glycosyl trehalose, hydrogenatedstarch hydrolysate, 1,2-hexanediol, mannitol, arginine, serine, sucrose,PCA, citnilline, glycogen, histidine HCl, alanine, threonine, glutamicacid, lysine HCl, phosphate buffered saline, creatine, cholesterylisostearate, cholesteryl chloride, cholesteryl nonanoate,butylhydroxytoluene (BHT), sodium dilauramidoglutamide lysine,maltodextrin, polyquaternium-39, cholecalciferol PEG-12 ether,saccharide isomerate, sorbitol, and derivatives thereof, but the presentinvention is not limited thereto.

The whitening component among the skin-modifying components may be awhitening component capable of improving the conditions of an areadamaged by melanin pigmentation, such as extracts derived from naturalmaterials such as animals, plants, minerals, and the like, amino acids,hormones, vitamins, and the like, but the present invention is notlimited thereto. For example, the whitening component may be one or moreselected from the group consisting of kojic acid, niacinamide, ascorbylglucoside, magnesium ascorbyl phosphate, acetyl tyrosine, fullerene,oryzanol, methoxy PEG-7 ascorbic acid, methyl undecenoyl leucinate,diacetyl benzoyllathyrol, protocatechuic aldehyde, alpha-bisabolol,dihydroxymethoxychalcone, acetylphytosphingosine, polydatin, diosmetin,azelaic acid, macelignan, a Panax ginseng root extract, a red ginsengroot extract, a scrophularia root extract, a lithospermum root extract,a Saururus chinensis extract, an agrimony extract, a Canna indica's rootextract, a Sasa quelpaertensis extract, a Sophora flavescens extract, acoix seed extract, an Atractylodis rhizoma alba extract, a wheat germextract, an Atractylodis rhizoma alba oil, and a Prunus domestica fruitextract.

The component for blocking ultraviolet rays among the skin-modifyingcomponents or the hair-modifying components may be an ultraviolet rayabsorbent such as a p-aminobenzoic acid derivative, a cinnamic acidderivative, a salicylic acid derivative, a benzophenone derivative, orthe like, an ultraviolet ray dispersing agent such as titanium oxide,zinc oxide, or the like, a resin such as a cellulose-based polymer, aPVP/alpha-olefin-based polymer, an acrylate polymer, a silicone resin, afluorine-modified silicone resin, or the like, or a polymer film-formingagent. A component having a substantial function of blocking ultravioletrays may be, for example, one or more selected from the group consistingof cinnamic acid, glyceryl PABA, drometrizole, digalloyl trioleate,3-(4-methylbenzylidene)camphor, menthyl anthranilate, benzophenone-3,benzophenone-4, benzophenone-8, butylmethoxy benzoylmethane, cinoxate,adenine riboside, octocrylene, octyl dimethyl PABA, octylmethoxycinnamate, octyl salicylate, octyl triazone, para-aminobenzoicacid, 2-benzimidazole-5-sulfonic acid, homosalate, zinc oxide, titaniumdioxide, isoamyl-p-methoxycinnamate, bis-ethylhexyloxyphenolmethoxyphenyltriazine, disodium phenyl dibenzimidazole tetrasulfonate,amodi-drometrizole trisiloxane, diethylhexyl butamido triazone,polysilicon-15 (dimethicodiethylbenzalmalonate), methylenebis-benzotriazolyl tetramethylbutylphenol, terephthalylidene dicamphorsulfonic acid, and a salt thereof, but the present invention is notlimited thereto.

The fragrance component among the skin-modifying components or thehair-modifying components may be, for example, aldehydes, phenols,alcohols, ethers, esters, hydrocarbons, ketones, lactones, musks,fragrances with a terpene skeleton, natural fragrances, animalfragrances, or the like. Non-limiting examples of the aldehydes includeundecylenic aldehyde, lauryl aldehyde, aldehyde C-12 MNA, myracaldehyde, α-amyl cinnamic aldehyde, cyclamen aldehyde, ethylvanillin,heliotropin, anisaldehyde, α-hexyl cinnamic aldehyde, octanal,ligustral, lilial, lyral, triplal, vanillin, helional, or the like.Non-limiting examples of the phenols include eugenol, isoeugenol, andthe like. Non-limiting examples of the alcohols include bacdanol,dihydromyrcenol, dihydrolinalool, linalool, nerol, santalol, santalex,terpineol, tetrahydrolinalool, phenylethyl alcohol, and the like.Non-limiting examples of the ethers include Cedramber, Grisalva,methyleugenol, methyl isoeugenol, and the like. Non-limiting examples ofthe esters include cis-3-hexenyl acetate, cis-3-hexenyl propionate,cis-3-hexenyl salicylate, p-cresyl acetate, p-tert-butylcyclohexylacetate, amyl acetate, methyl dihydrojasmonate, amyl salicylate, benzylsalicylate, benzyl benzoate, benzyl acetate, cedryl acetate, citronellylacetate, decahydro-62 -naphthyl acetate, dimethyl benzyl carbinylacetate, Erica propionate, ethyl acetoacetate, Erica acetate, geranylacetate, geranyl formate, hedione, linalyl acetate, β-phenylethylacetate, hexyl salicylate, styrallyl acetate, terpinyl acetate, yetiveryl acetate, o-tert-butylcyclohexyl acetate, manzanate, allylheptanoate, cinnamyl acetate, and the like. Non-limiting examples of thehydrocarbons include myrcene or the like. Non-limiting examples of theketones include α-ionone, β-ionone, methyl-β-naphthyl ketone,α-damascone, β-damascone, δ-damascone, cis-jasmone, methyl ionone, allylionone, cashmeran, dihydrojasmone, iso E Super, vertofix,isolongifolanone, Koavone, rose phenone, raspberry ketone, dynascone,and the like. Non-limiting examples of the lactones includeγ-decalactone, γ-undecalactone, γ-nonalactone, γ-dodecalactone,coumarin, ambroxan, and the like. Non-limiting examples of the musks mayinclude cyclopentadecanolide, ethylene brassylate, galaxolide, muskketone, tonalid, nitro musk, and the like. Non-limiting examples of thefragrances with a terpene skeleton include geraniol, nerol, linalool,citral, citronellol, menthol, mint, citronellal, myrcene, pinene,limonene, terpineol, carbone, ionone, camphor, borneol, and the like.Non-limiting examples of the natural fragrances include essential oilssuch as orange oil, lemon oil, lime oil, petitgrain oil, yuja oil,neroli oil, bergamot oil, lavender oil, lavandin oil, abies oil, aniseoil, bay oil, rosewood oil, ylang-ylang oil, citronella oil, geraniumoil, peppermint oil, menthol oil, spearmint oil, eucalyptus oil, lemongrass oil, patchouli oil, jasmine oil, rose oil, cedarwood oil, vetiveroil, galbanum oil, oakmoss oil, pine oil, camphor oil, sandalwood oil,hosho oil, turpentine oil, clove oil, black clove oil, cassia oil,netmeg oil, cananga oil, thyme oil, and the like. Non-limiting examplesof the animal fragrances include musk, citvet, castoreum, ambergris, andthe like.

The component for preventing or improving a wrinkle among theskin-modifying components may include extracts derived from naturalmaterials such as animals, plants, minerals, and the like, amino acids,hormones, vitamins, and the like, but the present invention is notlimited thereto. For example, the component for preventing or improvinga wrinkle may be one or more selected from the group consisting ofvitamin A (retinoids), vitamin E (tocopherols), flavonoids, polyphenols,superoxide dismutase (SOD). coenzyme Q10, alpha-lipoic acid, acetylhexapeptide, retinol, retinyl palmitate, retinyl acetate, adenosine,vitamin C, collagen, hexapeptide-3, epidermal growth factor (EGF),kinetin, snail slime, aquamide, ceramides, glycerine, hyaluronic acid,betaines, chitosan, urea, and derivatives thereof, but the presentinvention is not limited thereto.

The keratin care component among the skin-modifying components may be analpha hydroxyl acid (lactic acid, citric acid, mandelic acid, glycolicacid, tartaric acid, or the like), a beta hydroxy acid (salicylic acid,propanoic acid, hydroxypropionic acid, carnitine), a retinoidderivative, a vitamin A derivative, a Rhynchosia nulubilis extract,black soybean powder, a sugarcane extract, rice bran powder, Astrocaryummurumuru seed powder, nephrite powder, a hydrolyzed Cereus grandiflorusflower extract, thioglycolic acid, or the like, but the presentinvention is not limited thereto.

The component for preventing or improving dandruff and itching among theskin-modifying components may include extracts derived from naturalmaterials such as animals, plants, minerals, and the like, amino acids,hormones, vitamins, and the like, but the present invention is notlimited thereto. For example, the component for preventing or improvingdandruff and itching may be one or more selected from the groupconsisting of a moisturizing component such as ceramides, glycerine,hyaluronic acid, betaines, chitosan, vitamin E (tocopherols), and urea;a pharmaceutical hair growth agent including a vasodilator, a hairtonic, estrogen hormone, a hair root activating agent, and the like; ananti-inflammatory agent and a keratolytic agent such as d-panthenol,sulfur, resorcin, serine chloride, allantoin, AHA, salicylic acid, orthe like; an agent for preventing skin damage such as an astringent, arefrigerant, vitamin, hormone, antihistamine, or the like; a sebumsecretion inhibitor; an antibacterial agent such as trichlorocarbamide,tocopherol acetate, zinc pyrithione, benzalkonium chloride, benzethoniumchloride, chlorhexidine, hinokitiol, phenol, isopropyl methylphenol, orthe like; an antiseborrheic agent such as pyridoxine and a derivativethereof, or the like; an anti-inflammatory agent such as glychyrrhetinicacid and a derivative thereof, hydrocortisone acetate, hydrocortisonesuccinate, prednisolone, or the like; an antipruritic agent such asdiphenhydramine chloride, chlorophenylamine maleate, camphor, menthol,or the like; and other agents such as alanine glutamine, bisabolol,allantoin, coenzyme Q10, stearyl glycyrrhetinate (SG)/dipotassiumglycyrrhizinate (DPG), phytosphingosine and a derivative thereof.

The component for stimulating hair growth or stimulating hair regrowthamong the skin-modifying components or the hair-modifying components maybe a component for stimulating hair growth capable of filling a damagedportion of skin or hair, such as extracts derived from natural materialssuch as animals, plants, minerals, and the like, amino acids, peptides,proteins, sugars, vitamins, and the like, but the present invention isnot limited thereto. For example, the component for stimulating hairgrowth may be one or more selected from the group consisting of aSwertia japonica extract, carproniuin chloride, cepharanthin, benzylnicotinate, 1-menthol, estradiol, etynlyestradiol, pyridoxine HCl,salicylic acid, resorcin, benzalkonium chloride, benzethonium chloride,isopropyl methylphenol, piroctone olamine, climbazole, pantothenic acid,a placenta extract, biotin, mononitroguajacol, a photosensitizing dye,pentadecanoic acid glyceride, glycyrrhetinic acid, a potassium orammonium. salt of glycyrrhetinic acid, allantoin, minoxidil, steroids,estradiol benzoate, estrone, hydrocortisone (acetate), prednisolone,diphenhydramine HCl, dipotassium glycyrrhizinate, pyridoxinedicaprylate, tricosaccaride, tocopheroiltocopherol acetate, hinokitiol,dexpanthenol, pantothenyl ethylether, sodium/calcium pantothenate,isopropyl ethylphenol, mononitroaiajacol, chlorhexidine gluconatesolution, ethyl nicotinate, nicotinic acid amide, capsicum tincture,reisogen, cholesterol, swertiol, fused cystine, Sophora flavescenstincture, Asarum tincture, a Spirodela polythiza extract, a Swertiapseudochinensis extract, cepharanthin, gamma-oryzanol, cantharistincture, ginger tincture, nicotinic acid benzyl ester, vitamin A,vitamin B1, vitamin B2, vitamin B6, vitamin E, cystine, cysteine,methionine, leucine, tryptophan, glycerine, pyrrolidone carboxylate, andcamphor.

The component for preventing acne or inhibiting bacteria among theskin-modifying components may be a component for preventing acne orinhibiting bacteria capable of improving an area damaged by melaninpigmentation, such as extracts derived from natural materials such asanimals, plants, minerals, and the like, amino acids, hormones,vitamins, and the like, but the present invention is not limitedthereto. For example, the component for preventing acne or inhibitingbacteria may be one or more selected from the group consisting of asebum secretion inhibitor such as estradiol, estrone, orethynylestradiol; a keratolytic agent such as sulfur, salicylic acid, orresorcin; an antibacterial agent such as benzalkonium chloride,benzethonium chloride, halocarbon, or 2,4,4-trichloro-2-hydroxyphenol;an antibacterial agent for cosmetics, such as triclosan, trichlorocarbitol, isopropyl methylphenol, or pinyon; an anti-inflammatory agentsuch as allantoin, ϵ-aminocaproic acid, or glychyrrhetinic acid; and akeratolytic agent such as glycolic acid or the like.

The component for suppressing body odor among the skin-modifyingcomponents may be, for example, one or more selected from the groupconsisting of aluminum compounds such as aluminum chlorohydroxy,aluminum chlorohydroxy allantoinate, aluminum dihydroxy allantoinate,aluminum chloride, and aluminum potassium sulfate, benzethoniumchloride, halocarane, chlorhexidine hydrochloride, zinc oxide, zincp-phenolsulfonate, benzalkonium chloride, triclosan, thiram, a Psolareacorylifolia extract, a Pueraria lobata root extract, a lonicera japonicaflower extract, a Phyllostachyos caulis extract, an Acorus calamusextract, a Ginkgo biloba leaf extract, a Mouton radices cortex extract,a licorice extract, a Fallopian multiflora extract, a Houttuynia cordataextract, a Portulaca oleracea extract, pyroligneous liquor, bamboo salt,a grapefruit extract, a green tea extract, and a Paeonia lactifloraextract.

The component for atopic dermatitis care among the skin-modifyingcomponents may be a component for atopic dermatitis or skin trouble carewith an ability to significantly reduce or prevent atopic dermatitis orskin trouble due to having functions such as skin soothing,regeneration, immunity improvement, and the like, such as drugs derivedfrom natural materials such as animals, plants, minerals, and the like,fermented extracts, herbal ingredients, vitamins, and the like, but thepresent invention is not limited thereto. For example, the component foratopic dermatitis care may be one or more selected from the groupconsisting of ceramides, peptides, hyaluronic acid, glycerine,tacrolimus, pimecrolimus, clindamycin, erythromycin, tretinoin,adapalene, benzoyl peroxide, licorice, epidermal growth factor (EGF),peanut oil, Macadamia Ternifolia seed oil, propolis, an olive leafextract, a Siberian ginseng extract, a Houttuynia cordata extract, anarnica extract, and Sophora flavescens tincture. The peptides may be,specifically, wheat peptides, wheat-hydrolyzed peptides, keratinpeptides, keratin-hydrolyzed peptides, collagen peptides,collagen-hydrolyzed peptides, or the like, but the present invention isnot limited thereto.

The component for pore care among the skin-modifying components may beniacinamide, polyethoxylated retinamide, adenosine, menthol, awitch-hazel extract, ascorbic acid, kaolin, retinol, a Vitis viniferaroot extract, clays, asiaticoside, a Cynara scolymus leaf extract,glycosyl trehalose, hydrogenated starch hydrolysate, lecithin,tocopherols, charcoal powder, or the like, but the present invention isnot limited thereto.

The epilation component among the skin-modifying components may bethioglycolic acid, beeswax, a Narcissus tazetta bulb extract, a papayaextract, a Quercus dentata extract, or the like, but the presentinvention is not limited thereto.

The dye among the skin-modifying components or the hair-modifyingcomponents may include one or more atomic groups selected from the groupconsisting of —NO₂, —N═N—, C═O, C═C, C═N—, C═S, —N═O, and —N═NO as achromophore, but the present invention is not limited thereto. Also, thedye may include one or more atomic groups selected from the groupconsisting of —OCH₃, —N(CH₃)₂, —NH(CH₃), —NO₂, —CF₃, —OH, —Cl, and —NH₂as an auxochrome, but the present invention is not limited thereto. Inaddition, the dye may include one or more reactive groups selected fromthe group consisting of —COONa, —COOK, —COOH, —NH₂, —NHR, —NR₂, —Cl,—Br, —I, and —F, but the present invention is not limited thereto.Additionally, the dye may be a natural or synthetic dye used for hair,skin, fingernails and toenails, and the like. In this case, the naturaldye may be purpurin, munjistin, melanin, or a melanin precursor, but thepresent invention is not limited thereto. The synthetic dye may be RedNo. 3, Red No. 104, Red No. 105, Red No. 201, Red No. 202, Red No. 220,Red No. 227, Black No. 401, Red No. 230, Red No. 231, Red No. 232, RedNo. 401, Red No. 405, Yellow No. 4, Yellow No. 202, Orange No. 207, RedNo. 106, Red No. 213, Red No. 214, Red No. 215, Yellow No. 404, YellowNo. 405, Blue No. 403, Disperse Blue 1, Disperse Violet 1, DisperseOrange 3, Disperse Black 9, HC Blue 2, HC Red 3, HC Yellow 5, HC Red 1,Basic Orange 1, or Basic Orange 2, but the present invention is notlimited thereto.

The powder among the skin-modifying components may be titanium dioxide,hydroxyapatite, triethoxycaprylylsilane, aluminum hydroxide, zinc oxide,talc, mica, a yellow iron oxide, a red iron oxide, a black iron oxide,silica, an acrylate copolymer, guanine, guaiazulene, copper powder,aluminum stearate, orthoclase, zinc stearate, bronze powder, gardeniablue pigment, a Gardenia extract, gardenia yellow pigment, caramel,carmine, carbon, carbon black, copper chlorophyll, a henna leaf extract,a henna extract, Vitis vinifera powder, a Vitis vinifera skin extract, awine extract, a Vitis vinifera extract, loess, or the like, but thepresent invention is not limited thereto.

The component for fingernail and toenail care among the skin-modifyingcomponents may be a Viscum album extract, a Commelina communisleaf/flower/stem extract, dimethyltolylamine, methacryloyl ethylphosphate, a Commiphora abyssinica resin extract, butyl methacrylate,AMP-isostearoyl hydrolyzed silk, an Echinacea root extract, a Lyciumbarbarian fruit extract, urea peroxide, calcium peroxide, keratin,potassium hydroxide, hydrogen peroxide, hydrolyzed keratin, hydrolyzedcollagen, or the like, but the present invention is not limited thereto.

The bioconjugation component among the skin-modifying components or thehair-modifying components may be fibrin, albumin, glucosamine,n-acetylglucosamine, alginate, hydrogel, growth factors, bioactivefactors, a split hair bonding agent, an antibacterial coating agent, orthe like. The growth factors may be, for example, fibroblast growthfactors (FGFs), keratinocyte growth factors (KGFs), vascular endothelialgrowth factors (VEGFs), epidermal growth factors (EGFs), plateletderived growth factor AA (PDGF-AA), platelet derived growth factor AB(PDGF-AB), platelet derived growth factor BB (PDGF-BB), transforminggrowth factor-α (TGF-α), TGF-β, insulin-like growth factors (IGFs),tumor necrosis factors (TNFs), granulocyte macrophage colony stimulatingfactors (GM-CSFs), nerve growth factors (NGFs), or the like. Thebioactive factors may be interferons, hemopoietin, (interleukin-1),IL-2, IL-6, IL-8, or the like. The split hair bonding agent may beN-(4-carboxy-3-hydroxy-phenyl)maleimide, transglutaminase, lauryldiamine, or the like. The antibacterial coating agent may bebenzalkonium chloride, benzethonium chloride, halocarbon,2,4,4-trichloro-2-hydroxyphenol, triclosan, trichloro carbitol,isopropyl methylphenol, pinyon, allantoin, ϵ-aminocaproic acid,glychyrrhetinic acid, or the like, but the present invention is notlimited thereto.

The antibacterial component among the hair surface-modifying componentsmay be ceramides, glycerine, hyaluronic acid, betaines, chitosan,vitamin E (tocopherols), urea, d-panthenol, sulfur, resorcin, serinechloride, allantoin, AHA, salicylic acid, trichlorocarbamide, tocopherolacetate, zinc pyrithione, benzalkonium chloride, benzethonium chloride,chlorhexidine, hinokitiol, phenol, isopropyl methylphenol,phenoxyethanol, isothiazolinone, methylchloroisothiazolinone,pyridoxine, glychyrrhetinic acid, hydrocortisone acetate, hydrocortisonesuccinate, prednisolone, diphenhydramine chloride, chlorophenylaminemaleate, camphor, menthol, alanine glutamine, bisbolol, coenzyme Q10,stearyl glycyrrhetinate (SG)/dipotassium glycyrrhizinate (DPG),phytosphingosine, or a derivative thereof, but the present invention isnot limited thereto.

The term “fabric care component” used herein may be a component forsoftening a fabric, preventing damage caused by light, inhibiting orremoving a wrinkle, maintaining color, dyeing, removing contamination,imparting fragrance, removing an odor, inhibiting bacteria, preventingdamage caused by washing, waterproofing, coating, preventing staticelectricity, moisturizing, heat insulation or cold insulation,antioxidation, blocking ultraviolet rays, preventing fluff from beingentangled, or the like, but the present invention is not limitedthereto.

The component for softening a fabric, preventing damage, waterproofing,coating, preventing static electricity, and preventing fluff from beingformed and entangled may be, for example, dimethicone, trimethicone,phenyl trimethicone, amodimethicone, amodi phenyl trimethicone,amodi-penta phenyl trimethicone, dimethylpolysiloxane,methylphenylpolysiloxane, decamethylcyclopentasiloxane, methyltrimethicone, phenyl trimethicone, methicone, cyclomethicone, alkylmethyl siloxane, dimethicone copolyol, trimethylsilylamodimethicone, afluorine-based silicone compound, or the like, but the present inventionis not limited thereto.

In addition, the ceramide, which is effective in softening a fabric andpreventing damage, is a material with a structure in which a fatty acidis bonded to the amino group of a sphingosine, and the class ofceramides include natural/synthetic ceramides. For example, the ceramidemay be sphingosine, sphinganine, sphingenine, 2-amino-4-eicosane-1,3diol, ceramides, spingomyelin, cerebrosides, gangliosides,sphingolipids, or a derivative thereof, but the present invention is notlimited thereto.

The extract derived from a natural material used to increase the skinfriendliness of a fabric may be an algae extract, a Helianthus annuusseed extract, a Sophora flavescens extract, a Panax ginseng rootextract, a Coptis chinensis root extract, a Calendula officinalisextract, Betula platyphylla sap, a Betula alba extract, a Zanthoxylumbungeanum maxim extract, a Luffa cylindrical extract, a Monarda didymaextract, a Chamaecyparis obtusa extract, a Rhodiola rosea extract, aSophora flavescens extract, an Atractylodes rhizome extract, a Centellaasiatica extract, a Coptis chinensis extract, red ginseng root water, aFritillaria ussuriensis extract, a Convallaria keiskei extract, ahoneycomb extract, a cassis extract, a pomegranate extract, a lemonextract, a pine bud extract, a green tea extract, a broccoli extract, ahoney extract, a cranberry extract, a berry extract, a lavender extract,a lentil extract, a ginger extract, or the like. The protein and thepeptide may be a protein and a peptide which are obtained from Chun-zamsilk, silk, polylysine, algae, wool and hair, or wheat. The amino acidmay be glycine, alanine, valine, leucine, isoleucine, threonine, serine,cysteine, cystine, methionine, aspartic acid, asparagine, glutamic acid,diiodotyrosine, lysine, arginine, histidine, phenylalanine, tyrosine,tryptophan, proline, oxyproline, or the like, but the present inventionis not limited thereto.

The polymer used to form a coating on a fabric surface, improveprevention of a wrinkle, prevent dye migration, remove fluff duringwashing, impart elasticity to a fabric, and impart ease of ironing tothe fabric may be a linear/branched chain-type or network-type polymercompound having a molecular weight of about 1,000 to 1,000,000, mayinclude a double bond or various ring-structural substituents betweencarbon atoms as necessary, and preferably includes at least one residuewith reactivity in the molecule to attach a bioreactive group such as—COONa, —COOK, —COOH, —NH₂, —NHR, —NR₂, —Cl, —Br, —I, or —F for easilyattaching a bioreactive functional group to any one terminus of themolecule. More preferably, the polymer is a compound which is alinear/branched chain-type polymer having about 10,000 to 500,000 carbonatoms and includes at least one residue with reactivity in the moleculeto attach a bioreactive group such as —COONa, —COOK, —COOH —NH₂, —NHR,—NR₂, —Cl, —Br, —I, or —F for easily attaching a bioreactive functionalgroup to any one terminus of the molecule. For example, the polymer maybe a synthetic polymer such as an amphoteric polymer such as a polyaminepolymer, a polycarboxylic acid polymer, a methacryloyl ethylbetaine/methacrylate copolymer, or anoctylacrylamide/acrylatelbutylaminoethyl methacrylate copolymer; anonionic polymer such as polyvinylpyrrolidone (PVP), a PVP/vinyl acetate(VA) copolymer, or a PVP/dimethylaminoethyl methacrylate copolymer; oran anionic polymer such as an acrylate/methacrylate copolymer or aVA/crotonate/vinyl neodecanoate copolymer, or a natural polymer derivedfrom cellulose, guar, starch, or the like, but the present invention isnot limited thereto.

The dye, which serves to impart color to a fabric and maintain the same,may include one or more atomic groups selected from the group consistingof —NO₂, —N═N—, C═O, C═C, C═N—, C═S, —N═O, and —N═NO as a chromophore,but the present invention is not limited thereto. Also, the dye mayinclude one or more atomic groups selected from the group consisting of—OCH₃, —N(CH₃)₂, —NH(CH₃), —NO₂, —CF₃, —OH, —OCH₃, —Cl, and —NH, as anauxochrome, but the present invention is not limited thereto. Inaddition, the dye may include one or more reactive groups selected fromthe group consisting of —COONa, —COOK, —COOH, —NHR, —NR₂, —Cl, —Br, —I,and —F, but the present invention is not limited thereto.

Additionally, the dye may be a natural or synthetic dye used for hair,skin, a fabric, leather, and the like. In this case, the natural dye maybe purpurin, munjistin, melanin, or a melanin precursor, but the presentinvention is not limited thereto, and the synthetic dye may be Red No.3, Red No. 104, Red No. 105, Red No. 201, Red No. 202, Red No. 220, RedNo. 227, Black No. 401, Red No. 230, Red No. 231, Red No. 232. Red No.401, Red No. 405, Yellow No. 4. Yellow No. 202, Orange No. 207, Red No.106, Red No. 213, Red No. 214, Red No. 215, Yellow No. 404, Yellow No.405, Blue No. 403, Disperse Blue 1, Disperse Violet 1, Disperse Orange3, Disperse Black 9, HC Blue 2, HC Red 3, HC Yellow 5, HC Red 1, BasicOrange 1, or Basic Orange 2, but the present invention is not limitedthereto.

Examples of the component for removing contamination may include soaps,alkylbenzene sulfonates, alkane sulfonates, alpha-olefin sulfonates,alpha-sulfo fatty acid esters, alkyl sulfates, alkyl ether sulfates,alcohol ethoxylates, alkylphenol ethoxylates, fatty acid alkanolamides,alkylamine oxides, methylglucamides, alkyl polyglucosides, or the like,but the present invention is not limited thereto.

Examples of the component for imparting fragrance may include aldehydes,phenols, alcohols, ethers, esters, hydrocarbons, ketones, lactones,musks, fragrances with a terpene skeleton, natural fragrances, animalfragrances, and the like. Non-limiting examples of the aldehydes includeundecylenic aldehyde, lauryl aldehyde, aldehyde C-12 MNA, myracaldehyde, α-amyl cinnamic aldehyde, cyclamen aldehyde, ethylvanillin,heliotropin, anisaldehyde, α-hexyl cinnamic aldehyde, octanal,ligustral, lilial, lyral, triplal, vanillin, helional, and the like.Non-limiting examples of the phenols include eugenol, isoeugenol, or thelike. Non-limiting examples of the alcohols include bacdanol,dihydromyrcenol, dihydrolinalool, linalool, nerol, santalol, santalex,terpineol, tetrahydrolinalool, phenylethyl alcohol, and the like.Non-limiting examples of the ethers include Cedramber, Grisalva,methyleugenol, methyl isoeugenol, and the like. Non-limiting examples ofthe esters include cis-3-hexenyl acetate, cis-3-hexenyl propionate,cis-3-hexenyl salicylate, p-cresyl acetate, p-tert-butylcyclohexylacetate, amyl acetate, methyl dihydrojasmonate, amyl salicylate, benzylsalicylate, benzyl benzoate, benzyl acetate, cedryl acetate, citronellylacetate, decahydro-β-naphthyl acetate, dimethyl benzyl carbinyl acetate,Erica propionate, ethyl acetoacetate, Erica acetate, geranyl acetate,geranyl formate, hedione, linalyl acetate, β-phenylethyl acetate, hexylsalicylate, styrallyl acetate, terpinyl acetate, vetiveryl acetate,o-tert-butylcyclohexyl acetate, manzanate, allyl heptanoate, cinnamylacetate, and the like. Non-limiting examples of the hydrocarbons includemyrcene and the like. Non-limiting examples of the ketones includeα-ionone, β-ionone, methyl-β-naphthyl ketone, α-damascone, β-damascene,δ-damascone, cis-jasmone, methyl ionone, allyl ionone, cashmeran,dihydrojasmone, iso E Super, vertofix, isolongifolanone, Koavone, rosephenone, raspberry ketone, dynascone, and the like. Non-limitingexamples of the lactones include γ-decalactone, γ-undecalactone,γ-nonalactone, γ-dodecalactone, coumarin, ambroxan, and the like.Non-limiting examples of the musks include cyclopentadecanolide,ethylene brassylate, galaxolide, musk ketone, tonalid, nitro musk, andthe like. Non-limiting examples of the fragrance with a terpene skeletoninclude geraniol, nerol, linalool, citral, citronellol, menthol, mint,citronellal, myrcene, pinene, limonene, terpineol, carbone, ionone,camphor, borneol, and the like. Non-limiting examples of the naturalfragrance include an essential oil such as orange oil, lemon oil, limeoil, petitgrain oil, yuja oil, neroli oil, bergamot oil, lavender oil,lavandin oil, abies oil, anise oil, bay oil, rosewood oil, ylang-ylangoil, citronella oil, geranium oil, peppermint oil, spearmint oil,eucalyptus oil, lemon grass oil, patchouli oil, jasmine oil, rose oil,cedarwood oil, vetiver oil, galbanum. oil, oakmoss oil, pine oil,camphor oil, sandalwood oil, hosho oil, turpentine oil, clove oil, blackclove oil, cassia oil, netmeg oil, cananga oil, thyme oil, and the like.Non-limiting examples of the animal fragrance include musk, citvet,castoreum, ambergris, and the like.

The component for removing an odor may bemono-6-ethanediamine-6-deoxy-62 -cyclodextrin, α-cyclodextrin,β-cyclodextrin, α-cyclodextrin, cucurbituril, or the like, but thepresent invention is not limited thereto.

The antibacterial component may be a ceramide, glycerine, hyaluronicacid, betaines, chitosan, vitamin E (tocopherols), urea, d-panthenol,sulfur, resorcin, serin chloride, allantoin, AHA, salicylic acid,trichlorocarbamide, tocopherol acetate, zinc pyrithione, benzalkoniumchloride, benzethonium chloride, chlorhexidine, hinokitiol, phenol,isopropyl methylphenol, phenoxyethanol, isothiazolinone,methylchloroisothiazolinone, pyridoxine, glychyrrhetinic acid,hydrocortisone acetate, hydrocortisone succinate, prednisolone,diphenhydramine chloride, chlorophenylamine maleate, camphor, menthol,alanine glutamine, bisabolol, coenzyme Q10, stearyl glycyrrhetinate(SG)/dipotassium glycyrrhizinate (DPG), phytosphingosine, or aderivative thereof, but the present invention is not limited thereto.

The component for preventing static electricity may be stearylamidopropyl amine, isostearyl propyl amido amine, stearyl amido amine,isostearyl propyl amido amine, methyleicosanoic amidopropyl amine,methyleicosanoic amidoamine, behenyl amidopropyl amine, behenylamidoamine, or the like, but the present invention is not limitedthereto.

The moisturizing component which has effects of moisturizing a fabric,preventing and repairing a wrinkle, preventing static electricity,softening, and heat insulation or cold insulation induced by the actionof the fabric with water may be a moisturizing component capable offilling a damaged portion of the fabric, such as extracts derived fromnatural materials such as animals, plants, minerals, and the like, aminoacids, peptides, proteins, sugars, vitamins, and the like, but thepresent invention is not limited thereto. For example, the moisturizingcomponent may be one or more selected from the group consisting ofglycerin, propylene glycol, butylene glycol, dipropylene glycol,caprylyl glycol, diglycerin, methyl gluceth, ethoxydiglycol, glycereth,propanediol, diethoxydiglycol pyrrolidone carboxylic acid, sodiumlactate, sodium PCA, mineral oil, vaseline, lanolin, jojoba oil, oliveoil, glycosphingolipids, phospholipids, lipid composites, isononylisononanoate, betaines, carboxymethyl chitin, ceramides,glucosylceramide, glycosaminoglycans, alpha-glucans, hyaluronic acid,hydrolyzed hyaluronic acid, betaines, chitosan, chitosan succinimide,vitamin E (tocopherols), urea, hydroxyethyl urea, glucosides, gamma PGA,xylitylglucoside, xylitol, pentaerythrityl tetraisostearate, sodiumchondroitin sulfate, chondroitin-4-sulfate, atelocollagen, beta-glucan,PEG, pyridoxine tris-hexyl decanoate, potassium PCA, sodiumpolygamma-glutamate, polyglutamic acid, glyceryl polyacrylate,galactoarabinan, polyglycerin-3 crosspolymer, sodium hyaluronate,bis-PEG-18 methyl ether dimethyl silane, bis-ethoxydiglycol succinate,lecithin, ascorbyl tetraisopalmitate, glycosyl trehalose, hydrogenatedstarch hydrolysate, 1,2-hexanediol, mannitol, arginine, serine, sucrose,PCA, citrulline, glycogen, histidine HCl, alanine, threonine, glutamicacid, lysine HCl, phosphate buffered saline, creatine, cholesterylisostearate, cholesteryl chloride, cholesteryl nonanoate, BHT, sodiumdilauramidoglutamide lysine, maltodextrin, polyquaternium-39,cholecalciferol PEG-12 ether, saccharide isomerate, sorbitol, and aderivative thereof, but the present invention is not limited thereto.

The sugars which has effects of moisturizing a fabric, preventing andrepairing a wrinkle, preventing static electricity, softening, and heatinsulation or cold insulation induced by the action of the fabric withwater may be diose- to hexose-monosaccharides such as glycolaldehyde,glyceraldehyde, dihydroacetone, erythrose, erythrulose, ribose,arabinose, xylose, ribulose, xylulose, glucose, fructose, galactose, andmannose; disaccharides such as sucrose, maltose, lactose, trehalose, andmelibiose, cellobise; polysaccharides such as raffinose, melezitose,maltoriose, starchiose, oligosaccharides, galactooligosaccharides,isomaltooligosaccharide, fructooligosaccharides, xylan, araban, starch,dextrins, glycogen, cellulose, fructans, galactan, and mannan; orcomplex polysaccharides such as agar, algin, carrageenans, chitin,hemicelluloses, and pectin, but the present invention is not limitedthereto.

The antioxidation component which serves to prevent the fabric frombeing aged may be an antioxidation component with an ability tosignificantly reduce or prevent the destruction and depletion of thefunction and structure of the fabric damaged by oxidation, such asextracts derived from natural materials such as animals, plants,minerals, and the like, fermented extracts, amino acids, peptides,proteins, and the like, but the present invention is not limitedthereto. For example, the antioxidation component may be one or moreselected from the group consisting of acetamido caproic acid, acetylbenzoyloxy prasterone, acetylcysteine, 2-acetylhydroquinone,adamantanylcarboxamido hydroxylbenzamide, aminoethanesulfinic acid,aminopropyl ascorbyl phosphate, angoroside C, anserine, apigenin,arbutin, alpha-arbutin, ascorbic acid, asiaticoside, benzoguanamine,butylhydroxyanisol (BHA), butylated hydroxytoluene (BHT),bis-hydroxyethyl tocopherylsuccinoylamido hydroxypropane,bis-(tetramethyl hydroxypiperidinyl)sebacate), butylated xylenol,t-butylbenzamido hydroxylbenzamide, 4-butylresorcinol, caffeic acid,calcium ascorbate, carnosic acid, carotenoids, chitosan ascorbate,chlorogenic acid, cobalt DNA, copper adenosine triphosphate (ATP),copper pyridoxal 5-phosphate, curcumin, cysteine, cysteine hydrochloride(HCl), decapeptide-6, decapeptide-7, decursinol, decylmercaptomethylimidazole, diamylhydroquinone, di-t-butylhydroquinone,dicetyl thiodipropionate, dicyclopentadiene/t-butylcresol copolymer,digalloyl trioleate, diisooctyl sebacate, dilauryl thiodipropionate,dimethoxybenzamido phenylhydroxylacetamide, dimethoxy di-p-cresol,dimethylmethoxy chromanol, dimyristyl thiodipropionate, dioleyltocopheryl methylsilanol, diosmine, diretinyl ether, disodium ascorbylsulfate, distearyl thiodipropionate, ditridecyl thiodipropionate,dodecyl gallate, dunaliella bardawil powder, ellagic acid,epigallocatechin gallate, ergothioneine, Eriobotrya japonica leafprotoplasts, erythorbic acid, ethylbisiminomethylguaiacol manganesechloride, ethyl ferulate, ethylhexyl ferulate, ferulic acid, feruloylsoy glycerides, furfuryl palmitate, genistein glucoside, Ginkgo leafterpenoids, glucosylrutin, glyceryl chromonyl ether, glyceryldiferulate, hesperetin, hexyloxy trimethylphenol, honokiol, hydrolyzedproanthocyanidin, hydroquinone, p-hydroxyanisole, hydroxydecylubiquinone, hydroxylamine hydrochloride (HCl), hydroxylamine sulfate,hydroxyphenyl dihydroxybenzamide, inositol hexaniacinate hexaascorbate,isooctyl caprylate/caprate, isooctyl thioglycolate, isoquercitrin,kaempferol, kojic acid, kojyl glucoside, kojyl methylenedioxycinnamate,kou-cha ekisu, lycopene, madecassoside, magnesium ascorbate, magnolol,manganese adenosine triphosphate (ATP), matrine, melatonin, methoxyPEG-7 ascorbic acid, methoxytrimethylphenyl dihydroxyphenyl propanol,methyl di-t-butyl hydroxyhydrocinnamate, methylene di-t-butylcresol,methyl methacrylateltrimethoxysilylpropyl methacrylate crosspolymer,methyl myristic acid, niacinamide hydroxybenzoate, nictoflorin,nordihydroguaiaretic acid, octanicotinoyl epigallocatechin gallate,octapeptide-4, oligopeptide-28, paeonol, palmatine, PEG/PPG-2/5tocopheryl ether, perillyl alcohol, phenethyl caffeate, phenylethylresorcinol, phenylthioglycolic acid, phloretin, phloroglucinol,piceatannol, piperlonguminine, porphyridium polysaccharide, potassiumascorbyl tocopheryl phosphate, potassium sulfite, PPG-2 tocophereth-5,propyl gallate, protocatechuic aldehyde, puerarin, pyridoxinehydroxybenzoate, pyridyloxide t-butylnitrone, quercetin,resacetophenone, resorcinol, resveratrol, retinyl formyl aspartamate,rosmarinic acid, rutin, rutinyl succinate, ryoku-cha ekisu, salnacedin,sodium ascorbate, sodium sulfite, sodium tocopheryl phosphate, sodiumerythorbate, sodium phosphono-pyridoxylidenerhodanine, sodiumthioglycolate, sodium zinc histidine dithiooctanamide, sorbitylfurfural, stearyl gallate, succinoyl ascorbate pentapeptide-6,tangeritin, tert-butylhydroquinone (TBHQ), tetrabutylethylidinebisphenol, tetrahydrodemethoxydiferuloylmethane,tetrahydrocurcumin diacetate, tetrahydrodiferuloylmethane,tetramethylbutyl dihydroxybenzamide, tetramethylchromanol glucoside,thioctic acid, thiodiglycol, thiolactic acid, thiosalicylic acid,thioaurine, thymol trimethoxycinnamate, tococysteamide, tocophereth-5,tocopherols, tocophersolan, tocopheryl acetate, tocoquinone, toluene, otolyl biguanide, totarol, tripropylene glycol, tris-BHT mesitylene,tris(nonylphenyl)phosphite, trisodium ascorbyl isopalmitate phosphate,tyrosyl histidine hydrochloride (HCl), ubiquinol, ubiquinone, Ulvalactuca powder, uuron-cha ekisu, xylyl dibutylbenzofuranone, zincadenosine triphosphate (ATP), zinc dibutyldithiocarbamate, zinc fructosediphosphate, zinc pyridoxal 5-phosphate, and a derivative thereof, butthe present invention is not limited thereto.

The component for blocking ultraviolet rays, which is a main componenthaving effects of preventing damage caused by light and maintaining thecolor of the fabric may include an ultraviolet ray absorbent such as ap-aminobenzoic acid derivative, a cinnamic acid derivative, a salicylicacid derivative, a benzophenone derivative, or the like, an ultravioletray dispersing agent such as titanium oxide, zinc oxide, or the like, aresin such as a cellulose-based polymer, a PVP/alpha-olefin-basedpolymer, an acrylate polymer, a silicone resin, a fluorine-modifiedsilicone resin, or the like, and a polymer film-forming agent. Acomponent having a substantial function of blocking ultraviolet rays maybe, for example, one or more selected from the group consisting ofcinnamic acid, glyceryl PABA, drometrizole, trioleate,3-(4-methylbenzylidene)camphor, menthyl anthranilate, benzophenone-3,benzophenone-4, benzophenone-8, butylmethoxy benzoylmethane, cinoxate,adenine riboside, octocrylene, octyl dimethyl PABA, octylmethoxycinnamate, octyl salicylate, octyl triazone, para-aminobenzoicacid, 2-benzimidazole-5-sulfonic acid, homosalate, zinc oxide, titaniumdioxide, isoamyl-p-methoxycinnamate, bis-ethylhexyloxyphenolmethoxyphenyltriazine, disodium phenyl dibenzimidazole tetrasulfonate,amodi-drometrizole trisiloxane, diethylhexyl butamido triazone,polysilicon-15 (dimethicodiethylbenzalmalonate), methylenebis-benzotriazolyl tetramethylbutylphenol, terephthalylidene dicamphorsulfonic acid, and a salt thereof, but the present invention is notlimited thereto.

The skin surface-modifying component or the hair surface-modifyingcomponent may be used at a content of 0.0001 to 50 parts by weight,0.001 to 30 parts by weight, 0.01 to 10 parts by weight, or 0.1 to 5parts by weight with respect to 100 parts by weight of the entirecomposition. When it is used at a content of less than 0.0001 part byweight, there is a limitation in providing the effect of an activeingredient, and when it is used at a content of greater than 50 parts byweight, there is a problem in formulation and the stability offormulation over time, and the components may act as a component whichdoes not react and is lost.

The fabric care component may be used at a content of 0.0001 to 50 partsby weight, 0.001 to 30 parts by weight, 0.01 to 10 parts by weight, or0.1 to 5 parts by weight with respect to 100 parts by weight of theentire composition. When the fabric care component is used at a contentof less than 0.0001 part by weight, there is a limitation in exhibitingeffective performance, and when the fabric care component is used at acontent of greater than 50 parts by weight, there is a problem informulation and the stabilization of a formulation.

In particular, in the present invention, the skin surface-modifyingcomponent, the hair surface-modifying component, or the fabric carecomponent includes a carboxyl group, a hydroxyl group, a phosphategroup, or an amine group in a molecule thereof so that reactionefficiency with a carbodiimide-based compound may be increased.

In addition, in the present invention, the skin surface-modifyingcomponent, the hair surface-modifying component, or the fabric carecomponent may have a functional group capable of covalently bonding witha protein residue in a skin, hair, or fabric surface, or may furtherinclude a component containing a functional group capable of covalentlybonding with a protein residue in a skin, hair, or fabric surface.

The functional group capable of covalently bonding with a proteinresidue may be one or more selected from the group consisting ofcarbodiimides, imidoesters, aryl azides, diazirines, hydroxymethylphosphine, pentafluorophenyl esters, pyridyl disulfide,sulfo-hydroxysuccinimide esters, alkoxyamines, hydrazides, haloacetyls,azide, carbonates, aldehydes, propionaldehyde, butylaldehyde,nitrophenyl carbonate, aziridines, isocyanate, thiocyanate, epoxides,tresylates, succinimide, hydroxysuccinimidyl esters, imidazole,oxycarbonylamidazole, imines, thiols, maleimide, vinylsulfone,ethyleneimine, thioethers, acrylonitrile, acrylic or methacrylic acidester, disulfides, and ketones, but the present invention is not limitedthereto.

In addition, the functional group may react with a thiol, hydroxyl,carboxyl, or amine residue of an amino acid constituting a protein.

In a preferable embodiment of the surface modification composition orthe fabric care composition according to the present invention, a skin,hair, or fabric surface-modifying component having a carboxyl group isdirectly prepared in the form of a reactive ester surface-modifyingcomponent with bioreactivity, or an excessive amount of an amino acid(e.g., asparaginic acid or glutamic acid) present in the skin, hair, orfabric is subjected to reactive esterification, and thus prepared in theform of an ester with reactivity (reactive surface-modifying component)using a carbodiimide-based compound which a surface-modifying componenthaving an amine group can target to increase reaction efficiency, and asa result, an effect thereof may be significantly increased. Also, asurface-modifying component or a fabric care component, which targetsother amino acids or has a functional group such as carbodiimides,imidoesters, aryl azides, diazirines, hydroxymethyl phosphine,pentafluorophenyl esters, pyridyl disulfide, sulfo-hydroxysuccinimideesters, hydroxysuccinimide esters, alkoxyamines, hydrazides,haloacetyls, or azide, which reinforces the carbodiimide reaction, in amolecule thereof, may be additionally used to further increase an effectthereof.

In a more preferable embodiment, a carbodiimide-based compoundrepresented by Chemical Formula 1 may primarily react with a molecule ofa surface-modifying component having a carboxyl group or a proteinsurface of the skin, hair, or fabric to form a reactive ester, and thenthe reactive ester functional group thus formed may react with asurface-modifying component including amines in a molecule thereof orwith amines in a skin surface to obtain an excellent surfacemodification effect. When the reaction is performed at preferably pH 2to 10, more preferably pH 3 to 9, and most preferably pH 4 to 6.5, thatis, in an acidic to weak acidic aqueous solution, reaction efficiencymay be maximized. The reaction is completed in 1 to 30 minutes.

In Reaction Scheme 1 below, a schematic diagram of a reaction, in whicha molecule of a skin surface-modifying component including a carboxylgroup primarily reacts with a carbodiimide-based compound to form areactive ester, and then the reactive ester thus formed reacts with abiological amino acid having an amine residue to form a covalent bond,is illustrated.

In Reaction Scheme 2 below, a schematic diagram of a reaction, in whichasparaginic acid and glutamic acid, which are biological amino acids ina protein surface of skin and have a carboxyl group, primarily reactwith a carbodiimide-based compound to form a reactive ester, and thenthe reactive ester thus formed reacts with a skin surface-modifyingcomponent having an amine residue to faint a covalent bond, isillustrated.

Since the efficiency of a reaction between a protein of skin and a skinsurface-modifying component is increased due to a carbodiimide-basedcompound, the reactive skin surface-modifying component bonded to theskin may be not easily detached during general washing with a cleanser,a soap, or the like, but almost permanently attached to the skin.

In Reaction Scheme 3 below, a schematic diagram of a reaction, in whicha molecule of a hair surface-modifying component having a carboxyl groupprimarily reacts with a carbodiimide-based compound to form a reactiveester, and then the reactive ester thus formed reacts with a biologicalamino acid having an amine residue to form a covalent bond, isillustrated.

In Reaction Scheme 4 below, a schematic diagram of a reaction, in whichasparaginic acid and glutamic acid, which are biological amino acids ina protein surface of hair and include a carboxyl group, primarily reactwith a carbodiimide-based compound to form a reactive ester, and thenthe reactive ester thus formed reacts with a hair surface-modifyingcomponent having an amine residue to form a covalent bond, isillustrated.

Since the efficiency of a reaction between a protein of hair and a hairsurface-modifying component is increased due to a carbodiimide-basedcompound, a reactive hair surface-modifying component bonded to the hairmay be not easily detached during general washing with a shampoo, asoap, or the like, but almost permanently attached to the hair.

In Reaction Scheme 5 below, a schematic diagram of a reaction, in whicha molecule of a fabric care component having a carboxyl group primarilyreacts with a carbodiimide-based compound to form a reactive ester, andthen the reactive ester thus formed reacts with an amine residue to forma covalent bond, is illustrated.

In Reaction Scheme 6 below, a schematic diagram of a reaction, in whicha carboxyl group in a fabric surface primarily reacts with acarbodiimide-based compound to form a reactive ester, and then thereactive ester thus formed reacts with a fabric care component having anamine residue to form a covalent bond, is illustrated.

Since the efficiency of a reaction between a reactive residue in afabric and a fabric care component is increased due to acarbodiimide-based compound, a reactive fabric care component bonded tothe fabric may be not easily detached during general washing with adetergent, a soap, or the like, but almost permanently attached to thefabric.

In addition, in the present invention, the skin surface-modifyingcomponent, the hair surface-modifying component, or the fabric carecomponent may further include a reactive surface-modifying component(care component) bonded with a functional group capable of covalentlybonding with one or more proteins selected from the group consisting ofcarbodiimides, imidoesters, aryl azides, diazirines, hydroxymethylphosphine, pentafluorophenyl esters, pyridyl disulfide,sulfo-hydroxysuccinimide esters, alkoxyamines, hydrazides, haloacetyls,azide, carbonates, aldehydes, propionaldehyde, butylaldehyde,nitrophenyl carbonate, aziridines, isocyanate, thiocyanate, epoxides,tresylates, succinimide, hydroxysuccinimidyl esters, imidazole,oxycarbonylamidazole, imines, thiols, maleimide, vinylsulfone,ethyleneimine, thioethers, acrylonitrile, acrylic or methacrylic acidester, disulfides, and ketones.

For example, as shown in Reaction Schemes 1, 3, and 5, asurface-modifying component (care component) bonded with a carbodiimidegroup, which is produced by primarily reacting a carbodiimide-basedcompound, may be included. Also, the present invention may provide acomposition for surface modification including the reactivesurface-modifying component (care component).

In order to additionally increase an effect of the composition forsurface modification (care component) according to the present inventionin the formulation of the composition into cosmetics, the compositionmay be used in combination with a fatty acid such as palmitic acid,stearic acid, and the like, a fatty alcohol, a cationized polymer suchas a cationic surfactant including linear/branched long-chain alkylquaternary ammonium salts or the like, cationic cellulose, cationicguar, cationic polyvinylpyrrolidone, and the like, a silicone, or thelike for ease of formulation. Also, in order to formulate thecomposition as a cosmetic, components such as a solvent, a surfactant, athickening agent, a stabilizer, a preservative, a coloring agent, a pHcontrolling agent, a chelating agent, a coloring agent, a pearlescentagent, an appearance improving agent, a pigment, a particulate material,and the like may be additionally included. The component for formulationmay be used at a content of 0.0001 to 30 parts by weight with respect to100 parts by weight of the entire composition.

The composition for skin surface modification according to the presentinvention includes a skin surface-modifying component including afunctional group, and thus may be used in the skin care producttreatment. The skin care products generally are products for fresheningskin up and protecting skin, and may include all formulations that canbe applied to skin, including fundamental cosmetics (toners, serums,essences, lotions, creams, and the like), color cosmetics (makeup base,foundation, face powder, eye shadow, lip gloss, lipstick, lip balm, andthe like), cleansing cosmetics (foam cleansing, cleansing oils,cleansing lotions, cleansing creams, cleansing gels, packs, masks,soaps, cleansing tissues, and the like), sun care cosmetics (sun sprays,sunscreens, sunblocks, sun gels, and the like), body care cosmetics(body cleansers, body lotions, shower gels, bath salts, body creams,body oils, and the like), and fingernail and toenail care cosmetics(nail polishes, nail hardeners, coats, removers, nail dyes, nailtattoos, cuticle removers and oils).

The composition for hair surface modification according to the presentinvention includes a hair surface-modifying component including afunctional group, and thus may be used in the hair care producttreatment. The hair care products may include all formulations that canbe applied to hair, including shampoos, conditioners, treatments, hairpacks, hair essences, hair waxes, hair gels, hair sprays, hair mousses,hair dyes, hair bleaching products, hair perm products, hair tonics,hair regrowth products, hair growth promoters, hair root and scalpactivators, hair styling products, coating products, film formingagents, and the like.

The composition for fabric care according to the present inventionincludes a fabric care component including a functional group, and thusmay be used in the fabric care product treatment. The fabric careproducts may generally include fabric softeners, liquid detergents,powdered detergents, sheet type detergents, fabric dyes, fabrictreatments, fabric conditioners, bleaching products, stain removers,fabric styling products, ironing aids, preservatives, and the like.

More preferably, the composition for surface modification (carecomposition) according to the present invention includes acarbodiimide-based compound, and simultaneously includes a skinsurface-modifying component including a reactive functional group. Ifthe activity of the formulation is degraded when the formulation is inan aqueous environment, its activity is more easily maintained by beingin a non-aqueous form. Also, a reaction of the formulation may beinduced by mixing with a buffer solution immediately before use toadjust a pH or bringing in contact with water in a washing process.Examples of a non-aqueous form include liquid types, sheet types, powdertypes, tablet types, oils, wax, ampoules, gels, and the like, which arecommonly used as a non-aqueous cosmetic formulation. In addition, thecomposition may be prepared in the form of a single formulation in whichthe carbodiimide-based compound and the surface-modifying component(care component) are encapsulated, or in the form of two distinctformulations in which the carbodiimide-based compound and thesurface-modifying component (care component) are separated from eachother. Additionally, a method of blocking a derivative of the reactivefunctional group and the surface-modifying component (care component)bonded to each other from moisture through encapsulation may be used.

In order to increase a surface modification effect (care effect) of thecomposition for surface modification (care composition) including afunctional group according to the present invention, a dibasic acidester oil such as dioctyl succinate, di octyl adipate, diethyl sebacate,or the like, a polyol, polyethylene glycol, propylene glycol, hexyleneglycol, butanediol and an isomer thereof, glycerol, benzyl alcohol, orethoxydiglycol and a derivative thereof may be used. The solventmentioned above serves to increase permeability into the skin, hair, orfabric and is used as a solvent for a poorly soluble material. Morepreferably, diethyl sebacate, ethoxydiglycol, bis-ethoxydiglycolcyclohexane 1,4-dicarboxylate, or the like is used as a solvent used toincrease an effect of maintaining the activity of the surface-modifyingcomponent (care component) including a functional group.

Hereinafter, the present invention will be described in detail withreference to examples. However, the following examples are illustrativeof the present invention, and the present invention is not limited tothe following examples.

Comparative Examples 1 to 8 and Examples 1 to 4 Preparation of BodyCleanser

Compositions for a body cleanser, which contain sphingosine,amodimethicone, hyaluronic acid, or Red No. 227, which is generally usedin a body cleanser as a conditioning component, a component forimparting gloss to skin, a skin moisturizing component, or a dye forskin and nails, respectively, in compositions and quantities as listedin Table 1 below, and include no carbodiimide-based polymer (ComparativeExamples 1 to 4); benzene, 1,3-bis(1-isocyanato-1-methylethyl)-,homopolymer, polyethylene glycol mono-Me-ether-blocked as acarbodiimide-based polymer (Comparative Examples 5 to 8); or1,1′-methylene-bis-(3-isocyanatocyclohexane)-, homopolymer, polyethyleneglycol mono-Me-ether-blocked polymer which is a carbodiimide-basedpolymer of the present invention (Examples 1 to 4), were prepared.

TABLE 1 Compara- Compara- Compara- Compara- Compara- Compara- Compara-Compara- Exam- Exam- Exam- Exam- Composition tive Ex- tive Ex- tive Ex-tive Ex- tive Ex- tive Ex- tive Ex- tive Ex- ple ple ple ple (wt %)ample 1 ample 2 ample 3 ample 4 ample 5 ample 6 ample 7 ample 8 1 2 3 4Water 55   55   55   55   54   54   54   54   54   54   54   54  Polyquater- 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 nium-7 EDTA4Na  0.05  0.05  0.05  0.05  0.05  0.05  0.05  0.05  0.05  0.05  0.05 0.05 Lauric Acid 3   3   3   3   3   3   3   3   3   3   3   3  Myristic Acid 4   4   4   4   4   4   4   4   4   4   4   4   Sodiumlauryl 20   20   20   20   20   20   20   20   20   20   20   20   ether(2 moles) sulfate (30%) Cocamido- 15   15   15   15   15   15   15  15   15   15   15   15   propyl betaine (30%) Fragrance 0.9 0.9 0.9 0.90.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 Sphingosine 1   — — — 1   — — — 1   — —— Amodi- — 1   — — — 1   — — — 1   — — methicone Hyaluronic — — 1   — —— 1   — — — 1   — Acid Red No. 227 — — — 1   — — — 1   — — — 1  Benzene, 1,3- — — — — 1   1   1   1   — — — — bis(1-iso- cyanato-1-methyl- ethyl)-, homopolymer, polyethylene glycol mono-Me-ether-blocked 1,1′-methyl- — — — — — — — — 1   1   1   1   ene-bis-(3-isocyanato- cyclohexane)-, homopolymer, polyethylene glycol mono-Me-ether-blocked pH controlling Suitable Suitable Suitable SuitableSuitable Suitable Suitable Suitable Suit- Suit- Suit- Suit- agent amountamount amount amount amount amount amount amount able able able ableamount amount amount amount Total 100    100    100    100    100   100    100    100    100    100    100    100   

Experimental Example 1 Assessment of Conditioning, Gloss, Moisturizing,and Dyeing Effects

Each of the compositions for a body cleanser according to ComparativeExamples 1 to 8 and Examples 1 to 4 was used to wash a pig skin samplewith a size of 2 cm (width)×2 cm (length) ten times to induce surfacemodification, and each skin sample was washed three times with a 15%sodium lauryl ethyl sulfate solution (surfactant) to remove a componentwhich was not covalently bonded but just adsorbed onto the skin.Afterward, the skin samples thus treated were compared in terms of askin conditioning effect (sensory evaluation; five-level scale [5: verygood, 4: slightly good, 3: moderate, 2: slightly poor, 1: very poor];n=30), an increment in gloss determined by measuring the reflectivity oflight with a skin glossmeter, moisturizing using a skin conditioner, andredness measured with a color meter with those of untreated skinsamples, the result of which is shown in Table 2 below.

TABLE 2 Compara- Compara- Compara- Compara- Compara- Compara- Compara-Compara- Exam- Exam- Exam- Exam- tive Ex- tive Ex- tive Ex- tive Ex-tive Ex- tive Ex- tive Ex- tive Ex- ple ple ple ple Classification ample1 ample 2 ample 3 ample 4 ample 5 ample 6 ample 7 ample 8 1 2 3 4Conditioning 2.7 — — — 3.9 — — — 4.7 — — — effect Increment in — 5.2 — —— 17.6 — — — 46.5 — — gloss (%) Increment in — — 2.5 — — — 26.5 — — —48.7 — contained water (%) Increment in — — — 15.9 — — — 32.3 — — — 41.6redness (%)

As shown in Table 2, it was confirmed that Examples 1 to 4 including acarbodiimide-based polymer of the present invention exhibitedsignificantly excellent effects of skin conditioning and an increment ingloss, moisturizing, and redness caused by dyeing compared toComparative Examples 1 to 8.

Experimental Example 2

Compositions for a body cleanser were prepared using the samecompositions as in Examples 1 to 4 except that compounds listed in Table3 below were used instead of the carbodiimide-based compounds used inExamples 1 to 4. For the compositions for a body cleanser, a surfacemodification effect was assessed through the same method as inExperimental Example 1, the result of which is shown in Table 3 below.

TABLE 3 Skin Increment in conditioning Increment in contained Incrementin (five-level skin gloss water redness Compound scale) (%) (%) (%)1,3-Bis(isocyanatomethyl)cyclohexane-, 4.3 43.6 46.7 46.3 homopolymer,polyethylene glycol mono-Me-ether-blocked Benzene-1,3-diisocyanate-, 4.143.2 45.3 44.2 homopolymer, polyethylene glycol mono-Me-ether-blockedHexamethylene diisocyanate-, 4.0 42.2 44.6 44.1 homopolymer,polyethylene glycol mono-Me-ether-blocked PEG 600 diisocyanate-,homopolymer, 4.6 45.7 47.3 47.6 polyethylene glycol mono-Me-ether-blocked Diphenylmethane-2,2′-diisocyanate-, 4.5 45.0 46.9 46.6homopolymer, polyethylene glycol mono-Me-ether-blocked Isophoronediisocyanate-, 4.3 44.5 45.2 46.0 homopolymer, polyethylene glycolmono-Me-ether-blocked

Comparative Examples 9 to 14 and Examples 5 to 7 Preparation of BodyCleanser Composition

Compositions for a body cleanser, which contain niacinamide, hyaluronicacid, or salicylic acid, which is generally used as a skin whiteningcomponent, an anti-wrinkle component, or a keratin care component,respectively, in compositions and quantities as listed in Table 4 below,and include no carbodiimide-based polymer (Comparative Examples 9 to11); benzene, 1,3-bis(1-isocyanato-1-methylethyl)-, homopolymer,polyethylene glycol mono-Me-ether-blocked as a carbodiimide-based(Comparative Examples 12 to 14); or1,1′-methylene-bis-(3-isocyanatocyclohexane)-, homopolymer, polyethyleneglycol mono-Me-ether-blocked polymer which is a carbodiimide-basedpolymer of the present invention (Example 5 to 7), were prepared.

TABLE 4 Composition Comparative Comparative Comparative ComparativeComparative Comparative (wt %) Example 9 Example 10 Example 11 Example12 Example 13 Example 14 Example 5 Example 6 Example 7 Water 55   55  55   54   54   54   54   54   54   Polyquaternium-7 0.5 0.5 0.5 0.5 0.50.5 0.5 0.5 0.5 EDTA 4Na  0.05  0.05  0.05  0.05  0.05  0.05  0.05  0.05 0.05 Lauric Acid 3   3   3   3   3   3   3   3   3   Myristic Acid 4  4   4   4   4   4   4   4   4   Sodium lauryl ether (2 20   20   20  20   20   20   20   20   20   moles) sulfate (30%) Cocamidopropylbetaine 15   15   15   15   15   15   15   15   15   (30%) Fragrance 9  9   9   9   9   9   9   9   9   Nucleamide 1   — — 1   — — 1   — —Hyaluronic Acid — 1   — — 1   — — 1   — Salicylic acid — — 1   — — 1   —— 1   Benzene, 1,3-bis(1- — — — 1   1   1   — — — isocyanato-1-methylethyl)-, homopolymer, polyethylene glycol mono-Me-ether-blocked1,1′-methylene-bis-(3- — — — — — — 1   1   1   isocyanatocyclohexane)-,homopolymer, polyethylene glycol mono-Me-ether-blocked pH controllingagent Suitable Suitable Suitable Suitable Suitable Suitable SuitableSuitable Suitable amount amount amount amount amount amount amountamount amount Total 100    100    100    100    100    100    100   100    100   

Experimental Example 3 Assessment of Whitening, Wrinkle and KeratinImprovement Effect

Each group of 10 panelists who thought that they needed to managewhitening, a wrinkle, and keratin was asked to use each of thecompositions according to Comparative Examples 9 to 14 and Examples 5 to7 daily for 20 days and then use a general body cleanser for 10 days. Inthis case, satisfaction in terms of the degree of improvementimmediately after 20 days of use and the persistence of the effect after10 days was sensorially evaluated based on a five-level scale [5: verygood, 4: slightly good, 3: moderate, 2: slightly poor, 1: very poor],the result of which is shown in Table 5 below.

TABLE 5 Comparative Comparative Comparative Comparative ComparativeComparative Classification Example 9 Example 10 Example 11 Example 12Example 13 Example 14 Example 5 Example 6 Example 7 Whitening (1.7, 2.5)— — (3.5, 3.9) — — (4.2, 4.3) — — (improvement, persistence) Wrinkle —(1.9, 2.3) — — (3.7, 4.0) — — (4.5, 4.3) — (improvement, persistence)Keratin — — (1.2, 1.9) — — (3.4, 4.0) — — (4.7, 4.3) (improvement,persistence)

As shown in Table 5, it was confirmed that Examples 5 to 7 including acarbodiimide-based polymer of the present invention exhibitedsignificantly excellent effects of whitening, wrinkle care, and keratincare compared to Comparative Examples 9 to 14.

Experimental Example 4

Compositions for a body cleanser were prepared using the samecompositions as in Examples 5 to 7 except that compounds listed in Table6 below were used instead of the carbodiimide-based compound used inExamples 5 to 7. For the compositions for a body cleanser, a surfacemodification effect was assessed through the same method as inExperimental Example 3, the result of which is shown in Table 6 below.

TABLE 6 Whitening Wrinkle Keratin (improvement, (improvement,(improvement, persistence) persistence) persistence) (five-level(five-level (five-level Compound scale) scale) scale)1,3-Bis(isocyanatomethyl)cyclohexane-, (4.0, (4.4, (4.4, homopolymer,polyethylene glycol mono- 4.2) 4.0) 4.2) Me-ether-blockedBenzene-1,3-diisocyanate-, homopolymer, (4.0, (4.1, (4.3, polyethyleneglycol mono-Me-ether-blocked 4.1) 4.0) 4.1) Hexamethylene diisocyanate-,(3.9, (3.8, (4.0, homopolymer, polyethylene glycol mono- 4.1) 4.0) 4.0)Me-ether-blocked PEG 600 diisocyanate-, homopolymer, (4.0, (4.3, (4.5,polyethylene glycol mono-Me-ether-blocked 4.2) 4.3) 4.2)Diphenylmethane-2,2′-diisocyanate-, (4.0, (4.2, (4.3, homopolymer,polyethylene glycol mono- 4.1) 4.2) 4.2) Me-ether-blocked Isophoronediisocyanate-, homopolymer, (3.9, (4.0, (4.2, polyethylene glycolmono-Me-ether-blocked 4.1) 4.1) 4.1)

Comparative Examples 15 to 22 and Examples 8 to 11 Preparation ofShampoo Composition

Shampoo compositions for hair, which contain stearylamidopropyl amine,phenyl amodimethicone, polylysine, or chitosan polymer, which isgenerally used in hair shampoo as a conditioning component, aconditioning component for imparting gloss to hair, a conditioningcomponent for enhancing hair thickness, or a hair moisturizingcomponent, respectively, in compositions and quantities as listed inTable 7 below, and include no carbodiimide-based polymer (ComparativeExamples 15 to 18); benzene, 1,3-bis(1-isocyanato-1-methylethyl)-,homopolymer, polyethylene glycol mono-Me-ether-blocked as acarbodiimide-based polymer (Comparative Examples 19 to 22); or1,1′-methylene-bis-(4-isocyanatocyclohexane)-, homopolymer, polyethyleneglycol mono-Me-ether-blocked polymer which is a carbodiimide-basedpolymer of the present invention (Examples 8 to 11), were prepared.

TABLE 7 Compara- Compara- Compara- Compara- Compara- Compara- Compara-Compara- Exam- Exam- Exam- Exam- Composition tive Exam- tive Exam- tiveExam- tive Exam- tive Exam- tive Exam- tive Exam- tive Exam- ple ple pleple (wt %) ple 15 ple 16 ple 17 ple 18 ple 19 ple 20 ple 21 ple 22 1 910 11 Water 47   47   47   47   46   46   46   46   46   46   46   46  Polyquater- 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 nium-10 EDTA4Na  0.05  0.05  0.05  0.05  0.05  0.05  0.05  0.05  0.05  0.05  0.05 0.05 Sodium lauryl 35.0  35.0  35.0  35.0  35.0  35.0  35.0  35.0 35.0  35.0  35.0  35.0  ether (2 moles) sulfate (30%) Cocamido- 15.0 15.0  15.0  15.0  15.0  15.0  15.0  15.0  15.0  15.0  15.0  15.0  propylbetaine (30%) Fragrance 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9Stearyl amido- 1.0 — — 1.0 — — 1.0 — — — propyl amine Phenyl — 1.0 — —1.0 — — 1.0 — — amodimethi- cone Polylysine — — 1.0 — — 1.0 — — 1.0 —Chiman — — — 1.0 — — — 1.0 — — — 1.0 polymer Benzene, 1,3- — — — 1.0 1.01.0 1.0 — — — — bis(1-iso- cyanato-1- methylethyl)-, homopolymer,polyethylene glycol mono-Me- ether-blocked 1,1′-methyl- — — — — — — 1.01.0 1.0 1.0 ene-bis-(3- iso-cyanato- cyclohexane)-, homopolymer,polyethylene glycol mono-Me- ether-blocked pH controlling SuitableSuitable Suitable Suitable Suitable Suitable Suitable Suitable Suit-Suit- Suit- Suit- agent amount amount amount amount amount amount amountamount able able able able amount amount amount amount Total 100.0 100.0  100.0  100.0  100.0  100.0  100.0  100.0  100.0  100.0  100.0 100.0 

Experimental Example 5 Assessment of Conditioning and MoisturizingEffects

Each of the shampoo compositions according to Examples 8 to 11 and

Comparative Examples 15 to 22 was used to wash a hair tress having alength of 12 cm and a weight of 3 g ten times to induce surfacemodification, and each tress was washed three times with a 15% sodiumlauryl ethyl sulfate solution (surfactant) to remove a component whichwas not covalently bonded but just adsorbed onto the hair. Afterward,the hair tresses thus treated were compared in terms of an increment ineffects of conditioning (sensory evaluation; five-level scale [5: verygood, 4: slightly good, 3: moderate, 2: slightly poor, 1: very poor];n=30), gloss (determined by measuring reflectivity of light with a hairglossmeter), hair thickness (measured with an hair thickness measuringapparatus using a laser), and moisturizing (measured with a moisturizingmeasurement apparatus) with that of untreated hair tresses, the resultof which is shown in Table 8 below.

TABLE 8 Compara- Compara- Compara- Compara- Compara- Compara- Compara-Compara- Exam- Exam- Exam- Exam- tive Exam- tive Exam- tive Exam- tiveExam- tive Exam- tive Exam- tive Exam- tive Exam- ple ple ple pleClassification ple 15 ple 16 ple 17 ple 18 ple 19 ple 20 ple 21 ple 22 59 10 11 Conditioning 2.3 — — 3.7 — — — 4.5 — — — effect Increment in —1.2 — — 28 — — — 33 — — gloss (%) Increment in — — 0.25 — — 3.6 — — —7.3 — thickness (%) Water — — — 10.3 — — — 17.2 — — — 23.6 contained inhair (%)

As shown in Table 8, it was confirmed that Examples 8 to 11 including acarbodiimide-based polymer of the present invention exhibitedsignificantly excellent effects of conditioning, improving gloss,enhancing hair thickness, and moisturizing compared to ComparativeExamples 15 to 22.

Experimental Example 6

Shampoo compositions were prepared using the same compositions as inExamples 8 to 11 except that compounds listed in Table 9 below were usedinstead of the carbodiimide-based compound used in Examples 8 to 11. Forthe shampoo compositions, a surface modification effect was assessedthrough the same method as in Experimental Example 5, the result ofwhich is shown in Table 9 below.

TABLE 9 Hair Increment Increment Water conditioning in hair in haircontained (five-level gloss thickness in hair Compound scale) (%) (%)(%) 1,3-Bis(isocyanatomethyl)cyclohexane-, 4.3 48 7.2 24.3 homopolymer,polyethylene glycol mono- Me-ether-blocked Benzene-1,3-diisocyanate-,homopolymer, 4.1 45 6.9 24.0 polyethylene glycol mono-Me-ether- blockedHexamethylene diisocyanate-, 4.0 44 6.6 23.6 homopolymer, polyethyleneglycol mono- Me-ether-blocked PEG 600 diisocyanate-, homopolymer, 4.6 517.0 25.1 polyethylene glycol mono-Me-ether- blockedDiphenylmethane-2,2′-diisocyanate-, 4.4 49 6.8 24.8 homopolymer,polyethylene glycol mono- Me-ether-blocked Isophorone diisocyanate-,homopolymer, 4.4 47 6.6 24.0 polyethylene glycol mono-Me-ether- blocked

Comparative Examples 23 to 26 and Examples 12 to 13 Preparation ofShampoo Composition

Shampoo compositions, which contain Red No. 227 generally used in hairshampoo as a dyeing component or lauryl diamine with a structure capableof bonding split hair in compositions and quantities as listed in Table10 below, and include no carbodiimide-based polymer (ComparativeExamples 23 and 24); benzene, 1,3-bis(1-isocyanato-1-methylethyl)-,homopolymer, polyethylene glycol mono-Me-ether-blocked as acarbodiimide-based polymer (Comparative Examples 25 and 26); or1,1′-methylene-bis-(3-isocyanatocyclohexane)-, homopolymer, polyethyleneglycol mono-Me-ether-blocked polymer which is a carbodiimide-basedpolymer of the present invention (Examples 12 and 13), were prepared.

TABLE 10 Composition Comparative Comparative Comparative ComparativeExample Example (wt %) Example 23 Example 24 Example 25 Example 26 12 13Water 47   47   46   46   46   46   Polyquaternium-10  0.05  0.05  0.05 0.05  0.05  0.05 EDTA 4Na 35.0  35.0  35.0  35.0  35.0  35.0  Sodiumlauryl ether (2 moles) sulfate (30%) 15.0  15.0  15.0  15.0  15.0  15.0 Cocamidopropyl betaine (30%) Fragrance 0.9 0.9 0.9 0.9 0.9 0.9 Red No.228 1.0 — 1.0 — 1.0 — Lauryl diamine — 1.0 — 1.0 — 1.0 Benzene,1,3-bis(1- — — 1.0 1.0 — — isocyanato-1- methylethyl)-, homopolymer,piolyethylene glycol mono-Me-ether-blocked 1,1′-methylene-bis-(3- — — —— 1.0 1.0 isocyanatocyclohexane)-, homopolymer, polyethylene glycolmono-Me-ether-blocked pH controlling agent Suitable Suitable SuitableSuitable Suitable Suitable amount amount amount amount amount amountTotal 100.0  100.0  100.0  100.0  100.0  100.0 

Experimental Example 7 Assessment of Dyeing and Bioconjugation Effects

Each of the shampoo compositions according to Comparative Examples 23and 25 and Example 12 was used to wash a white yak hair tress ten times,and each of the shampoo compositions according to Comparative Examples24 and 26 and Example 13 was used to wash thirty end-split hair strandsten times to induce surface modification, and each tress was washedthree times with a 15% sodium lauryl ethyl sulfate solution (surfactant)to remove a component which was not covalently bonded but just adsorbedonto the hair. Afterward, the hair tresses thus treated were compared interms of an increment in redness using a color meter (in the case of theyak hair) or the repairing of split hair using a microscope (in the caseof the split hair), the results of which are shown in Table 11 below.

TABLE 11 Comparative Comparative Comparative Comparative Example ExampleClassification Example 23 Example 24 Example 25 Example 26 12 13Increment in 13 — 27 — 49 — redness (%) Bonding rate of — 0 — 35 — 48split hair (%)

As shown in Table 11, it was confirmed that Examples 12 and 13 includinga carbodiimide-based polymer of the present invention exhibitedsignificantly excellent dyeing and bioconjugation effects compared toComparative Examples 23 to 25.

Experimental Example 8

Shampoo compositions were prepared using the same compositions as inExamples 12 to 13 except that compounds listed in Table 9 below wereused instead of the carbodiimide-based compound used in Examples 12 and13. For the shampoo compositions, a surface modification effect wasassessed through the same method as in Experimental Example 7, theresult of which is shown in Table 12 below.

TABLE 12 Increment in Bonding rate of redness split hair Compound (%)(%) 1,3-Bis(isocyanatomethyl)cyclohexane-, homopolymer, 45 42polyethylene glycol mono-Me-ether-blocked Benzene-1,3-diisocyanate-,homopolymer, polyethylene 43 40 glycol mono-Me-ether-blockedHexamethylene diisocyanate-, homopolymer, 40 41 polyethylene glycolmono-Me-ether-blocked PEG 600 diisocyanate-, homopolymer, polyethylene47 46 glycol mono-Me-ether-blocked Diphenylmethane-2,2′-diisocyanate-,homopolymer, 45 45 polyethylene glycol mono-Me-ether-blocked Isophoronediisocyanate-, homopolymer, polyethylene 42 43 glycolmono-Me-ether-blocked

Comparative Examples 27 to 32 and Examples 14 to 16 Preparation ofFabric Detergent Composition

Compositions for a fabric detergent, which contain stearyl amidopropylamine, amodimethicone, ormono-(6-ethanediamine-6-deoxy)-beta-cyclodextrin, which is generallyused in a liquid laundry detergent as a component for preventing staticelectricity, a component for softening a fabric, or a component forremoving an odor, respectively, in compositions and quantities as listedin Table 13 below, and include no carbodiimide-based polymer(Comparative Examples 27 to 29); benzene,1,3-bis(1-isocyanato-1-methylethyl)-, homopolymer, polyethylene glycolmono-Me-ether-blocked as a carbodiimide-based polymer (ComparativeExamples 30 to 32); or 1,1′-methylene-bis-(3-isocyanatocyclohexane)-,homopolymer, polyethylene glycol mono-Me-ether-blocked polymer which isa carbodiimide-based polymer of the present invention (Examples 14 to16), were prepared.

TABLE 13 Composition Comparative Comparative Comparative ComparativeComparative Comparative Exam- Exam- Exam- (wt %) Example 27 Example 28Example 29 Example 30 Example 31 Example 32 ple 14 ple 15 ple 16 Water37.1  37.1  37.1  36.1  36.1  36.1  36.1  36.1  36.1  Lauryl sulfate20.0  20.0  20.0  20.0  20.0  20.0  20.0  20.0  20.0  Lauryl alcohol 7.00  7.00  7.00  7.00  7.00  7.00  7.00  7.00  7.00 ethoxylate (12moles) Lauric acid 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 4.0 Sodiumtriphosphate 10.0  10.0  10.0  10.0  10.0  10.0  10.0  10.0  10.0 Fragrance 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 0.9 Stearyl amidopropyl 1.0 —1.0 — 1.0 — — amine Amodimethicone — 1.0 — 1.0 — 1.0 — Mono-(6- — — 1.0— — 1.0 — — 1.0 ethanediamine-6- deoxy)-beta- cyclodextrin Benzene,1,3-bis(1- — — 1.0 1.0 1.0 — — — isocyanato-1- methylethyl)-homopolymer, polyethylene glycol mono-Me-ether-blocked1,1′-methylene-bis-(3- — — — — 1.0 1.0 1.0 isocyanatocyclohexane)-,homopolymer, polyethylene glycol mono-Me-ether-blocked Total 100.0 100.0  100.0  100.0  100.0  100.0  100.0  100.0  100.0 

Experimental Example 9 Assessment of Effects of Preventing StaticElectricity, Softening Fabric, and Removing Odor

The detergent compositions according to Comparative Examples 27 to 32and Examples 14 to 16 were used to wash a standard wool fabric with asize of 5 cm (width)×5 cm (length) ten times to induce surfacemodification, and each wool fabric was washed three times with a 15%sodium lauryl ethyl sulfate solution (surfactant) to remove a componentfor preventing static electricity, softening a fabric, or removing anodor, which was not covalently bonded but just adsorbed onto the fabric.Afterward, the wool fabrics thus treated were compared in terms ofeffects of preventing static electricity, softening a fabric, andremoving an odor (sensory evaluation; five-level scale [5: very good, 4:slightly good, 3: moderate, 2: slightly poor, 1: very poor]; n=30), theresult of which is shown in Table 14 below.

TABLE 14 Comparative Comparative Comparative Comparative ComparativeComparative Classification Example 27 Example 28 Example 29 Example 30Example 31 Example 32 Example 14 Example 15 Example 16 Staticelectricity 10.2 — — 35.6 — — 32.4 — — previous rate (%) Softeningeffect — 2.7 — — 3.0 — — 4.3 — (sensibility, five- level scale) Odorremoved — — 2.5 — — 3.9 — — 4.2 (same, five-level scale)

As shown in Table 14, it was confirmed that Examples 14 to 16 includinga carbodiimide-based polymer of the present invention exhibitedsignificantly excellent effects of preventing static electricity,softening a fabric, and removing an odor compared to ComparativeExamples 27 to 32.

Experimental Example 10

Detergent compositions were prepared using the same compositions as inExamples 14 to 16 except that compounds listed in Table 9 below wereused instead of the carbodiimide-based compound used in Examples 14 to16. For the detergent compositions, a surface modification effect wasassessed through the same method as in Experimental Example 9, theresult of which is shown in Table 15 below.

TABLE 15 Softening Static effect electricity (sensibility, Odor removalprevention rate five-level (sense, five- Compound (%) scale) levelscale) 1,3-Bis(isocyanatomethyl)cyclohexane-, 50.6 4.1 4.3 homopolymer,polyethylene glycol mono-Me- ether-blocked Benzene-1,3-diisocyanate-,homopolymer, 48.2 4.1 4.2 polyethylene glycol mono-Me-ether-blockedHexamethylene diisocyanate-, homopolymer, 45.3 4.0 4.0 polyethyleneglycol mono-Me-ether-blocked PEG 600 diisocyanate-, homopolymer, 50.14.2 4.4 polyethylene glycol mono-Me-ether-blockedDiphenylmethane-2,2′-diisocyanate-, 49.6 4.2 4.1 homopolymer,polyethylene glycol mono-Me- ether-blocked Isophorone diisocyanate-,homopolymer, 48.7 4.1 4.2 polyethylene glycol mono-Me-ether-blocked

Preparation Example 1 Preparation of Body Cleanser

Body cleansers as shown in Table 16 below were prepared through a commonmethod of preparing a body cleanser.

TABLE 16 Skin Wrinkle Keratin Conditioning gloss Moisturizing DyeingWhitening care care body body body body body body body Compositioncleanser cleanser cleanser cleanser cleanser cleanser cleanser Rawmaterial Content Content Content Content Content Content Content (%) (%)(%) (%) (%) (%) (%) Water 52.5  52.5  53   54.5  52.5  53   52.5 Polyquaternium-7 0.5 0.5 0.5 0.5 0.5 0.5 0.5 EDTA 4Na 0.1 0.1 0.1 0.10.1 0.1 0.1 Lauric acid 3.0 3.0 3.0 3.0 3.0 3.0 3.0 Myristic acid 4.04.0 4.0 4.0 4.0 4.0 4.0 Sodium lauryl ether (2 20.0  20.0  20.0  20.0 20.0  20.0  20.0  moles) sulfate (30%) Cocamidopropyl betaine 15.0 15.0  15.0  15.0  15.0  15.0  15.0  (30%) Fragrance 0.9 0.9 0.9 0.9 0.90.9 0.9 Sphingosine 2.0 — — — — — — Amodimethicone — 2.0 — — — — — RedNo. 227 — — — 0.2 — — — Niacinamide — — — — 2.0 — — Hyaluronic acid 0.50.5 2.0 0.5 0.5 2.0 0.5 Salicyclic acid — — — — — — 2.01,1′-methylene-bis-(3- 1.0 1.0 1.0 1.0 1.0 1.0 1.0isocyanatocyclohexane)-, homopolymer, polyethylene glycolmono-Me-ether-blocked pH controlling agent Suitable Suitable SuitableSuitable Suitable Suitable Suitable amount amount amount amount amountamount amount Total 100.0  100.0  100.0  100.0  100.0  100.0  100.0 

Preparation Example 2 Preparation of Skin Care Products (Whitening Mist,Lotion, Cream, and Pack)

Each of a mist, a lotion, a cream, and a pack as shown in Table 17 belowwas prepared through common methods of preparing a mist, a lotion, acream, and a pack.

TABLE 17 Whitening Whitening Whitening Whitening Composition (wt %) mistlotion cream pack Niacinamide 2.0 2.0 2.0 2.0 1,1′-methylene-bis-(3- 1.01.0 1.0 1.0 isocyanatocyclohexane)-, homopolymer, polyethylene glycolmono-Me-ether-blocked Glycerine 3.0 3.0 3.0 3.0 Butylene glycol 3.0 3.03.0 — Propylene glycol 3.0 3.0 — — Carboxyvinyl polymer 0.1 0.1 0.1 —Polyvinyl alcohol — — — 15.0  PEG-12 nonyl phenyl ether 0.3 — — 0.5Polysorbate 80 0.5 — — — Polysorbate 60 — 1.5 1.5 1.5 Sorbitansesquioleate — 1.5 — — Sorbitan stearate — — 0.5 — Liquid paraffin — 0.510.0  — Caprylic/capric triglyceride — 5.0 5.0 — Squalane — 5.0 5.0 —Cetearyl glucoside — — 2.0 — Ethanol 10.0  — — — Triethanolamine 0.1 0.10.1 — Stearyl alcohol — 1.0 — — Beeswax — 5.0 — — Preservative SuitableSuitable Suitable Suitable amount amount amount amount FragranceSuitable Suitable Suitable Suitable amount amount amount amount Purifiedwater buffer (pH 5.5) Remainder Remainder Remainder Remainder Total100.0  100.0  100.0  100.0 

Preparation Example 3 Preparation of Conditioning Shampoo

A hair conditioning shampoo as shown in Table 18 below was preparedthrough a common method of preparing a hair shampoo.

TABLE 18 Raw material Content Water 44.6 Polyquaternium-10 0.5 EDTA 4Na0.05 Sodium lauryl ether (2 moles) sulfate (30%) 35.0 Cocamidopropylbetaine (30%) 15.0 Fragrance 0.9 Stearyl amidopropyl amine 1.01,1′-methylene-bis-(3-isocyanatocyclohexane)-, homopolymer, 1.0polyethylene glycol mono-Me-ether-blocked pH controlling agent Suitableamount Total 100.0

Preparation Example 4 Preparation of Hair Product (Conditioning Mist,Lotion, Cream, and Pack)

Hair conditioning products as shown in Table 19 below were preparedthrough common methods of preparing a hair conditioning mist, lotion,cream, and pack.

TABLE 19 Conditioning Conditioning Conditioning Conditioning Composition(wt %) mist lotion cream pack Stearyl amidopropyl amine 1 1 1 1 Phenylamodimethicone 1 1 1 1 Polylysine 1 1 1 1 Chitosan polymer 1 1 1 11,1′-methylene-bis-(3- 1 1 1 1 isocyanatocyclohexane)-, homopolymer,polyethylene glycol mono-Me-ether-blocked Glycerine 3 3 3 3 Butyleneglycol 3 3 3 — Propylene glycol 3 3 — — Carboxyvinyl polymer   0.1   0.1  0.1 — Polyvinyl alcohol — — — 15  PEG-12 nonyl phenyl ether   0.3 — —  0.5 Polysorbate 80   0.5 — — — Polysorbate 60 —   1.5   1.5   1.5Sorbitan sesquioleate —   1.5 — — Sorbitan stearate — —   0.5 — Liquidparaffin —   0.5 10  — Caprylic/capric triglyceride — 5 5 — Squalane — 55 — Cetearyl glucoside — — 2 — Ethanol 10  — — — Triethanolamine   0.1  0.1   0.1 — Stearyl alcohol — 1 — — Beeswax — 5 — — PreservativeSuitable Suitable Suitable Suitable amount amount amount amountFragrance Suitable Suitable Suitable Suitable amount amount amountamount Purified water buffer (pH 4.5) Remainder Remainder RemainderRemainder

Preparation Example 5 Preparation of Laundry Detergent

A laundry detergent as shown in Table 20 below was prepared through acommon method of preparing a laundry detergent.

TABLE 20 Raw material Content (%) Water 54.1 Lauryl sulfate 20.0Laurylalcohol ethoxylate (12 moles) 7.00 Lauric acid 4.0 Sodiumtriphosphate 10.0 Fragrance 0.9 Stearyl amidopropyl amine 1.0Amodimethicone 1.0 mono-(6-ethanediamine-6-deoxy)-beta-cyclodextrin 1.01,1′-methylene-bis-(3-isocyanatocyclohexane)-, 1.0 homopolymer,polyethylene glycol mono-Me-ether-blocked Total 100.0

Preparation Example 6 Preparation of Fabric Softener

A laundry softener as shown in Table 21 below was prepared through acommon method of preparing a fabric softener.

TABLE 21 Raw material Content (%) Water 88 Isostearyl amine 0.5Distearyl dimethylammonium chloride 5.0 Stearyl amidopropyl amine 1.0Amodimethicone 1.0 mono-(6-ethanediamine-6-deoxy)-beta-cyclodextrin 1.01,1′-methylene-bis-(3-isocyanatocyclohexane)-, 1.0 homopolymer,polyethylene glycol mono-Me-ether-blocked Ethanol 1.0 Preservative,Antimicrobial agent Suitable amount Fragrance Suitable amount Total100.0

A composition for surface modification according to the presentinvention includes a reactive surface-modifying component (or a reactivefabric care component) including a specific functional group capable ofcovalently bonding with a protein residue of skin, hair, or a fabricand/or a specific carbodiimide-based compound so that covalent bondingis formed without causing damage to skin, hair, or a fabric, and thus askin or hair surface modification effect or a fabric care effect can besemi-permanently provided.

While the invention has been shown and described with reference tocertain exemplary embodiments thereof, it will be understood by thoseskilled in the art that various changes in form and details may be madetherein without departing from the spirit and scope of the invention asdefined by the appended claims.

1-10. (canceled)
 11. A composition for hair modification comprising: acarbodiimide-based compound represented by Chemical Formula 1 below; anda hair-modifying component:

wherein A represents a monomer which is one or more selected fromstructures listed below and has an isocyanate group (*) at both terminiof a repeat unit thereof, wherein the two As are homopolymers with thesame structure or heteropolymers with mutually different structures, Rrepresents hydrogen; C1 to C500 linear, branched, or cyclic hydrocarbon;or aromatic hydrocarbon, wherein a portion of the hydrocarbon moleculeincludes a double bond, is substituted with one or more elementsselected from the group consisting of O, N, S, P, and Si, is substitutedin an anionic, cationic, or amphoteric form, or is bonded with a metalion in a salt form, and m is an integer ranging from 1 to
 100.


12. A composition for hair modification comprising: a carbodiimide-basedcompound represented by Chemical Formula 2 below; and a hair-modifyingcomponent:

wherein A represents a monomer which is one or more selected fromstructures listed below and has an isocyanate group (*) at both terminiof a repeat unit thereof, wherein the two As are homopolymers with thesame structure or heteropolymers with mutually different structures, nis an integer ranging from 1 to 1,000, and m is an integer ranging from1 to
 100.


13. A composition for hair modification comprising: a carbodiimide-basedcompound represented by Chemical Formula 3 below; and a hair-modifyingcomponent:

wherein n is an integer ranging from 1 to 130, and m is an integerranging from 1 to
 20. 14. The composition for hair modificationaccording to claim 11, wherein the hair-modifying component is acomponent for antioxidation; conditioning; blocking ultraviolet rays;imparting fragrance; applying a dye; bioconjugation; inhibitingbacteria; stimulating hair growth; or stimulating hair regrowth.
 15. Thecomposition for hair modification according to claim 11, wherein thehair-modifying component has a carboxyl group, a hydroxyl group, aphosphate group, or an amine group in a molecule thereof.
 16. Thecomposition for hair modification according to claim 11, wherein thehair-modifying component has a functional group capable of covalentlybonding with a protein residue in a hair surface.
 17. The compositionfor hair modification according to claim 16, wherein the functionalgroup capable of covalently bonding with a protein residue is one ormore selected from the group consisting of imidoesters, aryl azides,diazirines, hydroxymethyl phosphine, pentafluorophenyl esters, pyridyldisulfide, sulfo-hydroxysuccinimide esters, alkoxyamines, hydrazides,haloacetyls, azide, carbonates, aldehydes, propionaldehyde,butylaldehyde, nitrophenyl carbonate, aziridines, isocyanate,thiocyanate, epoxides, tresylates, succinimide, hydroxysuccinimidylesters, imidazole, oxycarbonylamidazole, imines, thiols, maleimide,vinyl sulfone, ethyleneimine, thioethers, acrylonitrile, acrylic ormethacrylic acid ester, disulfides, and ketones.
 18. The composition forhair modification according to claim 11, wherein the carbodiimide-basedcompound is included at a content of 0.0001 to 10 parts by weight withrespect to 100 parts by weight of the entire composition.
 19. Thecomposition for hair modification according to claim 11, wherein thecomposition is prepared in the form of a single formulation in which thecarbodiimide-based compound and the hair-modifying component areencapsulated; or in the form of two distinct formulations in which thecarbodiimide-based compound and the hair-modifying component areseparated from each other.
 20. A hair care product comprising thecomposition for hair surface modification according to claim
 11. 21-30.(canceled)